Synthetic applications of metal-stabilized carbenium ions.IV. preparation of 1,5-ene-ynes via coupling of [(propargyl) dicobalt hexacarbonyl] cations with allyl silanes.

作者: Joseph E. O'Boyle , Kenneth M. Nicholas

DOI: 10.1016/S0040-4039(00)77762-8

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摘要: Abstract A highly selective and flexible route to 1,5-ene-ynes is provided by the reactions of [(propargyl) dicobalt hexacarbonyl] cations with allyl silanes.

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