Mild and selective deprotection of carbamates with Bu4NF
作者： Ulrich Jacquemard , Valérie Bénéteau , Myriam Lefoix , Sylvain Routier , Jean-Yves Mérour
DOI: 10.1016/J.TET.2004.07.071
关键词:
摘要: Abstract A new mild method allowing the removal of carbamates using TBAF in THF is reported. Reactions were performed on indole, indoline, N-methyl aniline, aniline and tryptamine derivatives. The observed selectivity according to or substrates discussed. mechanism postulated.
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