Experimental and numerical investigation of two‐phase flow patterns in magnesium electrolysis cell with non‐uniform current density distribution

作者: Cheng-Lin Liu , Ze Sun , Gui-Min Lu , Xing-Fu Song , Jian-Guo Yu

DOI: 10.1002/CJCE.22135

关键词:

摘要: In a magnesium electrolysis cell, the electrolyte flow pattern can be affected by chlorine gas bubbles release from anodes. A 2D gas-liquid mathematical model was developed to simulate liquid velocity and volume fraction. Particle Image Velocimetry (PIV) experimental set-up employed determine characteristics of field in cold validate model. The numerical results show good agreement with data. local production rate evolution is related anode current density according Faraday's law. To make bubble generation close reality, non-uniform distribution over surfaces, derived thermoelectric model, has been added as initial boundary conditions. According analysis, use conditions necessary. patterns side channels are found quite different that middle channels, where much lower. It noted both intensity size significantly affect fraction distributions. increased higher intensities larger size, enhanced lower diameters. Additionally, will decrease sharply when diameter smaller than critical value (0.9 mm). better keep for circulation.

参考文章(34)
P. Boissonneau, P. Byrne, An experimental investigation of bubble-induced free convection in a small electrochemical cell Journal of Applied Electrochemistry. ,vol. 30, pp. 767- 775 ,(2000) , 10.1023/A:1004034807331
H. RIEGEL, J. MITROVIC, K. STEPHAN, Role of mass transfer on hydrogen evolution in aqueous media Journal of Applied Electrochemistry. ,vol. 28, pp. 10- 17 ,(1998) , 10.1023/A:1003285415420
M. Elena Díaz, Alfredo Iranzo, Daniel Cuadra, Rubén Barbero, Francisco J. Montes, Miguel A. Galán, Numerical simulation of the gas–liquid flow in a laboratory scale bubble column: Influence of bubble size distribution and non-drag forces Chemical Engineering Journal. ,vol. 139, pp. 363- 379 ,(2008) , 10.1016/J.CEJ.2007.08.015
A. Alexiadis, M. P. Dudukovic, P. Ramachandran, A. Cornell, J. Wanngård, A. Bokkers, The Flow Pattern in Single and Multiple Submerged Channels with Gas Evolution at the Electrodes International Journal of Chemical Engineering. ,vol. 2012, pp. 392613- ,(2012) , 10.1155/2012/392613
Supathorn Phongikaroon, Ryan W. Bezzant, Michael F. Simpson, Measurements and analysis of oxygen bubble distributions in LiCl–KCl molten salt Chemical Engineering Research & Design. ,vol. 91, pp. 418- 425 ,(2013) , 10.1016/J.CHERD.2012.09.010
ANDERS A. DAHLKILD, Modelling the two-phase flow and current distribution along a vertical gas-evolving electrode Journal of Fluid Mechanics. ,vol. 428, pp. 249- 272 ,(2001) , 10.1017/S0022112000002639
Ze Sun, He-nan Zhang, Ping Li, Bing Li, Gui-min Lu, Jian-guo Yu, Modeling and Simulation of the Flow Field in the Electrolysis of Magnesium JOM. ,vol. 61, pp. 29- 33 ,(2009) , 10.1007/S11837-009-0066-Y
Mahmut D Mat, Kemal Aldas, Application of a two-phase flow model for natural convection in an electrochemical cell International Journal of Hydrogen Energy. ,vol. 30, pp. 411- 420 ,(2005) , 10.1016/J.IJHYDENE.2004.04.002
Hideki Tsuge, Kazuhiro Tozawa, Yukinori Muguruma, Masaki Kawabe, Masaki Abe, Masaru Sagiyama, Effect of Gas Holdup on Current Density Distribution in Horizontal Electrolysis Cell Canadian Journal of Chemical Engineering. ,vol. 81, pp. 707- 712 ,(2008) , 10.1002/CJCE.5450810349
A. Sokolichin, G. Eigenberger, A. Lapin, Simulation of buoyancy driven bubbly flow: Established simplifications and open questions Aiche Journal. ,vol. 50, pp. 24- 45 ,(2004) , 10.1002/AIC.10003