X-Ray absorption spectroscopic study of the AlPO4-5: ferrocene inclusion compound and its thermally decomposed products

作者: Astrid Lund , David G. Nicholson , Geraldine Lamble , Brian Beagley

DOI: 10.1039/JM9940401723

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摘要: The synthesis and decomposition of an inclusion compound, AlPO4: Fe(C5H5)2 is reported. This, the products have been characterised by extended X-ray absorption fine structure spectroscopy. clustering iron atoms either through Fe—Fe or Fe—O—Fe interactions shown to be absent. Instead, FeIII sited within double 6-rings 12-ring system. A model for distortions local lattice about proposed.

参考文章(23)
P.A. Jacobs, Mechanisms of Formation and Stabilization of Metals in the Pore Structure of Zeolites Studies in Surface Science and Catalysis. ,vol. 12, pp. 71- 85 ,(1982) , 10.1016/S0167-2991(09)60995-2
Paul E. Riley, Karl Seff, Crystallographic evidence for hydrolysis in zeolites. Structure of hydrated partially cobalt(II)-exchanged zeolite A The Journal of Physical Chemistry. ,vol. 79, pp. 1594- 1601 ,(1975) , 10.1021/J100582A025
Geoffrey A. Ozin, John Godber, Intrazeolite metallocenes: chemistry, spectroscopy, and dynamics The Journal of Physical Chemistry. ,vol. 93, pp. 878- 893 ,(1989) , 10.1021/J100339A066
Hok Nam Ng, Crispin Calvo, Refinement of the Crystal Structure of the Low-quartz Modification of Ferric Phosphate Canadian Journal of Chemistry. ,vol. 53, pp. 2064- 2067 ,(1975) , 10.1139/V75-287
Michael D. Lowery, Richard J. Wittebort, Michio Sorai, David N. Hendrickson, Dynamics of ferrocene in a thiourea inclusion matrix Journal of the American Chemical Society. ,vol. 112, pp. 4214- 4225 ,(1990) , 10.1021/JA00167A017
A. L. Roe, D. J. Schneider, R. J. Mayer, J. W. Pyrz, J. Widom, L. Que, X-ray absorption spectroscopy of iron-tyrosinate proteins Journal of the American Chemical Society. ,vol. 106, pp. 1676- 1681 ,(1984) , 10.1021/JA00318A021
Karin Moller, Aticha Borvornwattananont, Thomas Bein, Chemistry of cyclopentadienyliron dicarbonyl dimer and ferrocene in zeolite Y cavities: anchoring organometallic fragments into microporous solids The Journal of Physical Chemistry. ,vol. 93, pp. 4562- 4571 ,(1989) , 10.1021/J100348A034
S J Gurman, N Binsted, I Ross, A rapid, exact, curved-wave theory for EXAFS calculations. II. The multiple-scattering contributions Journal of Physics C: Solid State Physics. ,vol. 19, pp. 1845- 1861 ,(1986) , 10.1088/0022-3719/19/11/021
N. Motta, M. De Crescenzi, A. Balzarotti, Structural and electronic properties of Fe and TiFe from extended and near-edge x-ray-absorption structure Physical Review B. ,vol. 27, pp. 4712- 4721 ,(1983) , 10.1103/PHYSREVB.27.4712
Vasant R Choudhary, Deepak B Akolekar, Site energy distribution and catalytic properties of microporous crystalline AlPO4-5 Journal of Catalysis. ,vol. 103, pp. 115- 125 ,(1987) , 10.1016/0021-9517(87)90098-4