Comparative study of homochiral and racemic chiral metal-organic frameworks built from camphoric acid

摘要: The study of the crystallization homochiral or racemic chiral framework materials from enantiopure ligands is an important step for rational design crystalline materials. self-assembly extended frameworks in presence regulated by differing symmetry requirements ligand. By employing both and as cross-linking ligands, we have prepared three compounds their synthesis structural topological properties are presented here. It shown that depending on chemical compositions topologies, effect ligand handedness resulting crystal structure can vary greatly. negligible crystallization, which leads to interesting example two pairs isostructural achiral structures with types six-connected nets. In another reported here, ch...