Synthesis and Crystal Structure of Decavanadate-Based Coordination Polymers
作者： Kang P. Jin , Hai J. Jiang , Yan Wang , Da P. Zhang , Jie Mei
DOI: 10.1007/S10876-018-1391-5
关键词:
摘要: Two base-decavanadates coordination polymers [H2V10O28]0.5Ni(phen)3 (1) and [(C4H14N2)2]·[Zn(H2O)6][V10O28]·6H2O (2) (phen = 1,10-phenanthroline) have been synthesized characterized. They composed by the ligand, transition metal ions, decavanadates, both compounds are stable three-dimensional supramolecular structure due to exist of a multitude hydrogen bonding interactions. The modes similar in 1 2 as six-coordinated octahedral structures. However, their atoms manifestly different. Ni atom is coordinated with ligand phen nitrogen atom, zinc oxygen water. electrochemical measurement cyclic voltammetric electrocatalytic activities shows that good properties peroxide reductive.
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