Synthesis, structures, and magnetic properties of metal–organic polyhedra based on unprecedented {V7} isopolyoxometalate clusters
作者： Yu-Teng Zhang , Shuang-Bao Li , Xin-Long Wang , Ya-Ru Gong , Kui-Zhan Shao
DOI: 10.1039/C6DT02764D
关键词: Vanadium 、 Polyhedron 、 Isostructural 、 Crystallography 、 MOPS 、 Building unit 、 Inorganic chemistry 、 Metal 、 Chemistry
摘要: Two isostructural vanadium-based metal–organic polyhedra (denoted as VMOP-16 and VMOP-17) were synthesized by a solvothermal method, which are built from unprecedented {V7} isopolyoxometalate clusters dicarboxylate ligands. To our knowledge, the second building unit is reported for first time features highest nuclearity of vanadium–oxygen compared with MOPs.
rsc.org
sci-hub.se 参考文章(38)
Dong-Ying Du, Jun-Sheng Qin, Shun-Li Li, Zhong-Min Su, Ya-Qian Lan, Recent advances in porous polyoxometalate-based metal-organic framework materials. Chemical Society Reviews. ,vol. 43, pp. 4615- 4632 ,(2014) , 10.1039/C3CS60404G
Shou-Tian Zheng, Jie Zhang, Guo-Yu Yang, Designed Synthesis of POM–Organic Frameworks from {Ni6PW9} Building Blocks under Hydrothermal Conditions Angewandte Chemie. ,vol. 47, pp. 3909- 3913 ,(2008) , 10.1002/ANIE.200705709
A. W. Augustyniak, M. Fandzloch, M. Domingo, I. Łakomska, J. A. R. Navarro, A vanadium( iv ) pyrazolate metal–organic polyhedron with permanent porosity and adsorption selectivity Chemical Communications. ,vol. 51, pp. 14724- 14727 ,(2015) , 10.1039/C5CC05913E
Yu-Teng Zhang, Xin-Long Wang, En-Long Zhou, Xue-Song Wu, Bai-Qiao Song, Kui-Zhan Shao, Zhong-Min Su, Polyoxovanadate-based organic–inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages Dalton Transactions. ,vol. 45, pp. 3698- 3701 ,(2016) , 10.1039/C5DT04764A
Aleksandar Kondinski, Thomas Heine, Kirill Yu. Monakhov, Rotational Isomerism, Electronic Structures, and Basicity Properties of “Fully-Reduced” V14-type Heteropolyoxovanadates Inorganic Chemistry. ,vol. 55, pp. 3777- 3788 ,(2016) , 10.1021/ACS.INORGCHEM.5B02636
Marie-Pierre Santoni, Giuseppina La Ganga, Viviana Mollica Nardo, Mirco Natali, Fausto Puntoriero, Franco Scandola, Sebastiano Campagna, The Use of a Vanadium Species As a Catalyst in Photoinduced Water Oxidation Journal of the American Chemical Society. ,vol. 136, pp. 8189- 8192 ,(2014) , 10.1021/JA5040182
Jinjie Qian, Feilong Jiang, Kongzhao Su, Qipeng Li, Daqiang Yuan, Maochun Hong, Self-assembly of polyhedral indium-organic nanocages. Inorganic Chemistry. ,vol. 53, pp. 12228- 12230 ,(2014) , 10.1021/IC501728Z
De-Liang Long, Eric Burkholder, Leroy Cronin, Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices Chemical Society Reviews. ,vol. 36, pp. 105- 121 ,(2007) , 10.1039/B502666K
Yu-Teng Zhang, Xin-Long Wang, Shuang-Bao Li, Ya-Ru Gong, Bai-Qiao Song, Kui-Zhan Shao, Zhong-Min Su, Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal–organic polyhedra Chemical Communications. ,vol. 52, pp. 9632- 9635 ,(2016) , 10.1039/C6CC04583A
Yuanzhe Gao, Yingnan Chi, Changwen Hu, Organic-functionalized, substituted polyoxovanadium and vanadoniobates: Synthesis, structure and application Polyhedron. ,vol. 83, pp. 242- 258 ,(2014) , 10.1016/J.POLY.2014.08.018