Organic-functionalized, substituted polyoxovanadium and vanadoniobates: Synthesis, structure and application

作者: Yuanzhe Gao , Yingnan Chi , Changwen Hu

DOI: 10.1016/J.POLY.2014.08.018

关键词:

摘要: Abstract Polyoxovanadates (POVs), as an important subfamily of polyoxometalates (POMs), have been attracting continuous interest due to their rich structural chemistry and unusual properties that make them attractive for applications in catalysis, magnetism, optics medicine. In parallel with the large number crystal structures isopolyoxovanadates reported literature, incorporation heteroatoms into polyoxovanadate frameworks towards functional materials has received considerable attention. This mini-review summarizes recent advances on polyoxovanadates, particularly highlights achievements are concerned organic-functionalized, substituted polyoxovanadium vanadoniobates. We present synthetic methods, features mainly catalysis magnetism. The challenges prospects these emerging polyoxovanadates also discussed.

参考文章(138)
Dennis J. Eichorst, Kevin E. Howard, David A. Payne, Scott R. Wilson, Crystal structure of lithium niobium ethoxide (LiNb(OCH2CH3)6: a precursor for lithium niobate ceramics Inorganic Chemistry. ,vol. 29, pp. 1458- 1459 ,(1990) , 10.1021/IC00333A003
Michael Thor Pope, Heteropoly and isopoly oxometalates Inorganic chemistry concepts. ,vol. 8, ,(1983) , 10.1007/978-3-662-12004-0
Yanfei Qi, Yangguang Li, Enbo Wang, Hua Jin, Zhiming Zhang, Xinlong Wang, Song Chang, Syntheses and structures of four organic–inorganic hybrids based on the surface restricted building unit and various zinc coordination groups Inorganica Chimica Acta. ,vol. 360, pp. 1841- 1853 ,(2007) , 10.1016/J.ICA.2006.09.021
Jian Zhou, Shou-Tian Zheng, Wei-Hui Fang, Guo-Yu Yang, A New 2-D Network Containing {As4V16O42(H2O)} Cluster Units European Journal of Inorganic Chemistry. ,vol. 2009, pp. 5075- 5078 ,(2009) , 10.1002/EJIC.200900596
Markus Piepenbrink, Michael U. Triller, Neville H. J. Gorman, Bernt Krebs, Bridging the Gap between Polyoxometalates and Classic Coordination Compounds: A Novel Type of Hexavanadate Complex Angewandte Chemie International Edition. ,vol. 41, pp. 2523- 2525 ,(2002) , 10.1002/1521-3773(20020715)41:14<2523::AID-ANIE2523>3.0.CO;2-#
Ming-Lai Fu, Guo-Cong Guo, A-Qing Wu, Bin Liu, Li-Zhen Cai, Jin-Shun Huang, Synthesis, Crystal Structure and Characterisation of a Novel Chiral Mixed‐Valence Vanadium Oxide Hybrid, [V5O11(dien)3] European Journal of Inorganic Chemistry. ,vol. 2005, pp. 3104- 3108 ,(2005) , 10.1002/EJIC.200500055
Rebecca H. Laye, Qiang Wei, Pamela V. Mason, Maheswaran Shanmugam, Simon J. Teat, Euan K. Brechin, David Collison, Eric J. L. McInnes, A highly reduced vanadium(III/IV) polyoxovanadate comprising an octavanadyl square-prism surrounding a dimetallic vanadium(III) fragment. Journal of the American Chemical Society. ,vol. 128, pp. 9020- 9021 ,(2006) , 10.1021/JA062723+
Dong Hou, Gyu-Shik Kim, Karl S. Hagen, Craig L. Hill, Synthesis and characterization of a polyvanadate polyester involving a monodentate alcohol, [(n-C4H9)4N][V6O12(OCH3)7] Inorganica Chimica Acta. ,vol. 211, pp. 127- 130 ,(1993) , 10.1016/S0020-1693(00)85590-5
Jong Woo Han, Craig L Hill, None, A Coordination Network That Catalyzes O2-Based Oxidations Journal of the American Chemical Society. ,vol. 129, pp. 15094- 15095 ,(2007) , 10.1021/JA069319V