作者: Yuanzhe Gao , Yingnan Chi , Changwen Hu
DOI: 10.1016/J.POLY.2014.08.018
关键词:
摘要: Abstract Polyoxovanadates (POVs), as an important subfamily of polyoxometalates (POMs), have been attracting continuous interest due to their rich structural chemistry and unusual properties that make them attractive for applications in catalysis, magnetism, optics medicine. In parallel with the large number crystal structures isopolyoxovanadates reported literature, incorporation heteroatoms into polyoxovanadate frameworks towards functional materials has received considerable attention. This mini-review summarizes recent advances on polyoxovanadates, particularly highlights achievements are concerned organic-functionalized, substituted polyoxovanadium vanadoniobates. We present synthetic methods, features mainly catalysis magnetism. The challenges prospects these emerging polyoxovanadates also discussed.