Synthesis of full and semi Interpenetrating hydrogel from polyvinyl alcohol and poly (acrylic acid-co-hydroxyethylmethacrylate) copolymer: Study of swelling behavior, network parameters, and dye uptake properties
作者： Bidyadhar Mandal , Samit Kumar Ray , Ruma Bhattacharyya
DOI: 10.1002/APP.35298
关键词:
摘要: Semi and full interpenetrating network (IPN) hydrogels were synthesized by allowing free radical copolymerization of acrylic acid (AA) hydroxyethyl methacrylate (HEMA) in the matrix polyvinyl alcohol (PVOH). Accordingly, four different semi IPN prepared with PVOH: copolymer mass ratio 1 : 1, 0.75, 0.5, 0.25. These designated as SEMIIPN1, SEMIIPN2, SEMIIPN3, SEMIIPN4, respectively. In all these SEMIIPN, after polymerization PVOH was crosslinked 2 % glutaraldehyde to form structure. a similar way, sequential from AA HEMA (designated PAAHEMA) same composition except this case apart crosslinking PAAHEMA further N,N′-methylenebisacrylamide (NMBA) produce FULLIPN1, FULLIPN2, FULLIPN3, FULLIPN4. All type characterized carboxylic %, FTIR, UV, DTA-TGA, XRD, SEM, mechanical properties. The parameters, swelling diffusion characteristics also studied. performance IPNs compared terms their relative abilities for removing varied concentration rhodamine B (RB) methyl Violet (MV) dyes water. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
sci-hub.se 参考文章(24)
Qunwei Tang, Xiaoming Sun, Qinghua Li, Jihuai Wu, Jianming Lin, A simple route to interpenetrating network hydrogel with high mechanical strength Journal of Colloid and Interface Science. ,vol. 339, pp. 45- 52 ,(2009) , 10.1016/J.JCIS.2009.07.026
A. Gupta, R. Kumar, N. K. Upadhyay, P. Surekha, P. K. Roy, Synthesis, characterization and efficacy of chemically crosslinked PVA hydrogels for dermal wound healing in experimental animals Journal of Applied Polymer Science. ,vol. 111, pp. 1400- 1408 ,(2009) , 10.1002/APP.28990
Hatice Bodugoz-Senturk, Celia E. Macias, Jean H. Kung, Orhun K. Muratoglu, Poly(vinyl alcohol)–acrylamide hydrogels as load-bearing cartilage substitute Biomaterials. ,vol. 30, pp. 589- 596 ,(2009) , 10.1016/J.BIOMATERIALS.2008.10.010
S.B. Kuila, S.K. Ray, Paramita Das, N.R. Singha, Synthesis of full interpenetrating network membranes of poly(acrylic acid-co-acrylamide) in the matrix of polyvinyl alcohol for dehydration of ethylene glycol by pervaporation Chemical Engineering and Processing. ,vol. 50, pp. 391- 403 ,(2011) , 10.1016/J.CEP.2011.02.011
Gulay Bayramoglu, Begum Altintas, M. Yakup Arica, Adsorption kinetics and thermodynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin. Chemical Engineering Journal. ,vol. 152, pp. 339- 346 ,(2009) , 10.1016/J.CEJ.2009.04.051
Linda F. Gudeman, Nikolaos A. Peppas, pH-sensitive membranes from poly(vinyl alcohol)/poly(acrylic acid) interpenetrating networks Journal of Membrane Science. ,vol. 107, pp. 239- 248 ,(1995) , 10.1016/0376-7388(95)00120-7
Rupali Gangopadhyay, Amitabha De, Conducting semi-IPN based on polyaniline and crosslinked poly(vinyl alcohol) Synthetic Metals. ,vol. 132, pp. 21- 28 ,(2002) , 10.1016/S0379-6779(02)00212-6
Isadora Reis Rodrigues, Maria Madalena de Camargo Forte, Denise Scherman Azambuja, Katia R.L. Castagno, Synthesis and characterization of hybrid polymeric networks (HPN) based on polyvinyl alcohol/chitosan Reactive & Functional Polymers. ,vol. 67, pp. 708- 715 ,(2007) , 10.1016/J.REACTFUNCTPOLYM.2007.05.010
Y Murali Mohan, PS Keshava Murthy, K Mohana Raju, None, Synthesis, characterization and effect of reaction parameters on swelling properties of acrylamide–sodium methacrylate superabsorbent copolymers Reactive & Functional Polymers. ,vol. 63, pp. 11- 26 ,(2005) , 10.1016/J.REACTFUNCTPOLYM.2005.01.005
Jumi Yun, Hyung-Il Kim, Preparation of poly(vinyl alcohol)/poly(acrylic acid) microcapsules and microspheres and their pH-responsive release behavior Journal of Industrial and Engineering Chemistry. ,vol. 15, pp. 902- 906 ,(2009) , 10.1016/J.JIEC.2009.09.021