Investigations of preferential solvation on some poly(siloxane-azomethine)s containing dihydroxyanthraquinone units
作者： A. Airinei , M. Homocianu , A. Vlad , M. Cazacu
DOI: 10.1016/J.MOLLIQ.2013.07.011
关键词:
摘要: Abstract UV/VIS absorption and emission spectra of some polyazomethines containing dihydroxyanthraquinone units siloxane moieties have been investigated in solvents different polarities. The Catalan solvent scale was used for describing the solvatochromic shifts bands. influence composition binary mixtures on solvation maxima studied. following were utilized: methanol-dimethyl sulfoxide (MeOH-DMSO), chloroform-DMSO (CHCl 3 -DMSO) chloroform-methanol -MeOH). preferential parameters local mole fraction (X 2 ), excess function (δ s2 ) constant (K PS determined.
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sci-hub.se 参考文章(33)
İskender Yilgör, James E. McGrath, Polysiloxane containing copolymers: A survey of recent developments Springer, Berlin, Heidelberg. pp. 1- 86 ,(1988) , 10.1007/BFB0025274
Bradley M. Luther, Joel R. Kimmel, Nancy E. Levinger, Dynamics of polar solvation in acetonitrile–benzene binary mixtures: Role of dipolar and quadrupolar contributions to solvation Journal of Chemical Physics. ,vol. 116, pp. 3370- 3377 ,(2002) , 10.1063/1.1436074
Maria Cazacu, Carmen Racles, Mihaela Alexandru, Aurelia Ioanid, Angelica Vlad, Morphology and surface properties of some siloxane–organic copolymers Polymer International. ,vol. 58, pp. 697- 702 ,(2009) , 10.1002/PI.2581
E. Apostolova, S. Krumova, N. Tuparev, M.T. Molina, Ts. Filipova, I. Petkanchin, S.G. Taneva, Interaction of biological membranes with substituted 1,4-anthraquinones Colloids and Surfaces B: Biointerfaces. ,vol. 29, pp. 1- 12 ,(2003) , 10.1016/S0927-7765(02)00179-0
Angshuman Maitra, Sanjib Bagchi, Study of solute–solvent and solvent–solvent interactions in pure and mixed binary solvents Journal of Molecular Liquids. ,vol. 137, pp. 131- 137 ,(2008) , 10.1016/J.MOLLIQ.2007.06.002
Scott Grecian, Aaron D. Wrobleski, Jeffrey Aubé, Regioselective single and double conjugate additions to substituted cyclohexa-2,5-dienone monoacetals. Organic Letters. ,vol. 7, pp. 3167- 3170 ,(2005) , 10.1021/OL050715C
Angelica Vlad, Maria Cazacu, Grigore Munteanu, Anton Airinei, Petru Budrugeac, Polyazomethines derived from polynuclear dihydroxyquinones and siloxane diamines European Polymer Journal. ,vol. 44, pp. 2668- 2677 ,(2008) , 10.1016/J.EURPOLYMJ.2008.05.014
Rafael Gómez, Raúl Blanco, Dirk Veldman, José L Segura, René AJ Janssen, None, Synthesis and photophysical properties of conjugated polymers with pendant 9,10-anthraquinone units. Journal of Physical Chemistry B. ,vol. 112, pp. 4953- 4960 ,(2008) , 10.1021/JP711327K
Javier Catalán, Toward a Generalized Treatment of the Solvent Effect Based on Four Empirical Scales: Dipolarity (SdP, a New Scale), Polarizability (SP), Acidity (SA), and Basicity (SB) of the Medium Journal of Physical Chemistry B. ,vol. 113, pp. 5951- 5960 ,(2009) , 10.1021/JP8095727
V. Sasirekha, M. Umadevi, V. Ramakrishnan, Solvatochromic study of 1,2-dihydroxyanthraquinone in neat and binary solvent mixtures. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 69, pp. 148- 155 ,(2008) , 10.1016/J.SAA.2007.03.021