Solvatochromic study of 1,2-dihydroxyanthraquinone in neat and binary solvent mixtures.
作者： V. Sasirekha , M. Umadevi , V. Ramakrishnan
DOI: 10.1016/J.SAA.2007.03.021
关键词:
摘要: Abstract Preferential solvation of a solvatochromic probe has been studied in binary mixtures comprising non-protic and protic solvent. The solvents employed are carbon tetrachloride (CCl4), acetonitrile (AcN) N,N-dimethyl formamide (DMF) the methanol (MeOH) ethanol (EtOH). molecule exhibits different spectroscopic characteristics depending upon properties solubilizing media. observed spectral features provide an indication microenvironment immediately surrounding probe. Solvatochromic shifts ground excited states were analysed by monitoring charge transfer absorption band fluorescence emission spectra terms solute–solvent solvent–solvent interactions. Fluorescence show dual due to state proton nature molecule. effect solvent excitation energy on also studied. magnitude Stokes shift above used deduce experimentally dipole moment ratio for state. is higher than
harvard.edu
elsevier.com
sci-hub.se 参考文章(30)
Corinna Emmeluth, Volker Dyczmons, Martin A. Suhm, Tuning the Hydrogen Bond Donor/Acceptor Isomerism in Jet-Cooled Mixed Dimers of Aliphatic Alcohols† Journal of Physical Chemistry A. ,vol. 110, pp. 2906- 2915 ,(2006) , 10.1021/JP0540407
Z. Yoshida, F. Takabayashi, Electronic spectra of mono-substituted anthraquinones and solvent effects Tetrahedron. ,vol. 24, pp. 933- 943 ,(1968) , 10.1016/0040-4020(68)88043-3
S. Murcia-Mascarós, C. Domingo, S. Sanchez-Cortes, M. V. Cañamares, J. V. Garcia-Ramos, Spectroscopic identification of alizarin in a mixture of organic red dyes by incorporation in Zr-Ormosil Journal of Raman Spectroscopy. ,vol. 36, pp. 420- 426 ,(2005) , 10.1002/JRS.1315
Sung Haeng Cho, Hyun Huh, Hyung Min Kim, Choong Ik Kim, Nam Joon Kim, Seong Keun Kim, Laser induced fluorescence and resonant two-photon ionization spectroscopy of jet-cooled 1-hydroxy-9,10-anthraquinone Journal of Chemical Physics. ,vol. 122, pp. 034304- 034304 ,(2005) , 10.1063/1.1829977
Mario P. Marzocchi, Anna R. Mantini, Maurizio Casu, Giulietta Smulevich, Intramolecular hydrogen bonding and excited state proton transfer in hydroxyanthraquinones as studied by electronic spectra, resonance Raman scattering, and transform analysis Journal of Chemical Physics. ,vol. 108, pp. 534- 549 ,(1998) , 10.1063/1.475417
Steven R. Flom, Paul F. Barbara, Proton transfer and hydrogen bonding in the internal conversion of S1 anthraquinones The Journal of Physical Chemistry. ,vol. 89, pp. 4489- 4494 ,(1985) , 10.1021/J100267A017
Paul F. Barbara, Patrick K. Walsh, Louis E. Brus, Picosecond kinetic and vibrationally resolved spectroscopic studies of intramolecular excited-state hydrogen atom transfer The Journal of Physical Chemistry. ,vol. 93, pp. 29- 34 ,(1989) , 10.1021/J100338A011
M.R. Reta, J.D. Anunziata, R.I. Cattana, J.J. Silber, Comparison between solvatochromic and chromatographic studies of anthraquinones in binary aqueous mixtures Analytica Chimica Acta. ,vol. 306, pp. 81- 89 ,(1995) , 10.1016/0003-2670(94)00595-D
B. Giese, C. Reichardt: Solvent Effects in Organic Chemistry, Monographs in Modern Chemistry, Vol. 3. Verlag Chemie, Weinheim, New York 1979. 355 Seiten, Preis: DM 108,- Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 84, pp. 519- 519 ,(1980) , 10.1002/BBPC.19800840520
Jun Rye Choi, Sae Chae Jeoung, Dae Won Cho, Two-photon-induced excited-state intramolecular proton transfer process in 1-hydroxyanthraquinone Chemical Physics Letters. ,vol. 385, pp. 384- 388 ,(2004) , 10.1016/J.CPLETT.2004.01.011