Infrared Spectroscopic Evidence for Protonated Water Clusters Forming Nanoscale Cages

作者: Mitsuhiko Miyazaki , Asuka Fujii , Takayuki Ebata , Naohiko Mikami

DOI: 10.1126/SCIENCE.1096037

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摘要: Size-dependent development of the hydrogen bond network structure in largesized clusters protonated water, H+(H2O)n (n = 4 to 27), was probed by infrared spectroscopy OH stretches. Spectral changes with cluster size demonstrate that chain structures at small sizes ≲ 10) develop into two-dimensional net (∼10

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