Effects of iron(III) chloro-complexes on the polymerization of styrene—II: Retardation and inhibition kinetics in dimethyl sulphoxide
作者： N.N. Dass , M.H. George
DOI: 10.1016/0014-3057(71)90152-2
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摘要: Abstract A kinetic study has been made of the polymerization styrene in dimethyl sulphoxide (DMSO) at 60°, initiated by 2,2′-azobisisobutyronitrile presence Fe(DMSO)63+ and Fe (DMSO)5 Cl2+ complex ions. Velocity constants for polystyryl radical attack on Fe(DMSO)5Cl2+ ions are 0·229 71·8 m3 mol−1 sec−1, respectively, 60°.
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