Thermal Redox Reactions Between Metal Ions and Radicals in Aqueous Solutions
作者： E. COLLINSON , F. S. DAINTON , B. MILE , S. TAZUKE , D. R. SMITH
DOI: 10.1038/198026A0
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摘要: Thermal redox reactions between metal ions and radicals in aqueous solutions were investigated. Results are reported from measurements of rate constants for involved the x or gamma irradiation acrylamide containing a metallic compound. Systems with Fe III, Cu II, Ti Ag I, Hg Eu II used. Reactions oxidation polyacrylamide radicals, reduction hydrogen atoms, hydroxyl effects on discussed. (C.H.)
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sci-hub.se 参考文章(7)
Henry Taube, BRIDGING AND NON-BRIDGING LIGAND EFFECTS IN REDOX REACTIONS OF METAL IONS Canadian Journal of Chemistry. ,vol. 37, pp. 129- 137 ,(1959) , 10.1139/V59-019
R. A. Marcus, On the Theory of Oxidation‐Reduction Reactions Involving Electron Transfer. I The Journal of Chemical Physics. ,vol. 24, pp. 966- 978 ,(1956) , 10.1063/1.1742723
Jacob Bigeleisen, Spectral and Reactivity Differences of Transition Metal Ions in H2O and D2O Journal of Chemical Physics. ,vol. 32, pp. 1583- 1584 ,(1960) , 10.1063/1.1730976
D. J. Mackinnon, William A. Waters, 63. The possible significance of Fenton's reaction in relation to oxidations effected by enzyme systems Journal of the Chemical Society (Resumed). pp. 323- 328 ,(1953) , 10.1039/JR9530000323
F. S. Dainton, M. Tordoff, The polymerization of acrylamide in aqueous solution. Part 3.—The hydrogen peroxide photosensitized reaction at 25° C Trans. Faraday Soc.. ,vol. 53, pp. 499- 511 ,(1957) , 10.1039/TF9575300499
C. E. H. Bawn, D. Verdin, The reactions of αα-diphenyl-β-picryl hydrazyl with inorganic ions Transactions of The Faraday Society. ,vol. 56, pp. 519- 527 ,(1960) , 10.1039/TF9605600519
J. Halpern, Homogeneous Catalytic Activation of Molecular Hydrogen by Metal Ions and Complexes The Journal of Physical Chemistry. ,vol. 63, pp. 398- 403 ,(1959) , 10.1021/J150573A015