Structure, luminescence properties and energy transfer of Tb3+–Eu3+ codoped LiBaB9O15 phosphors
作者： Ting Li , Panlai Li , Zhijun Wang , Shuchao Xu , Qiongyu Bai
DOI: 10.1039/C5DT01849H
关键词:
摘要: A series of single-composition phosphors LiBaB9O15:Tb3+,Eu3+ have been prepared via a high-temperature solid-state reaction process. The structure and luminescence properties are described. LiBaB9O15:Tb3+ phosphor shows characteristic green emission, with the peak located at 551 nm, which corresponds to 5D4 → 7F5 transition Tb3+. LiBaB9O15:Eu3+ presents an obvious red 617 is ascribed 5D0 7F2 Eu3+. highly intense emission peaks Eu3+ ions were attributed effective energy transfer from Tb3+ in LiBaB9O15:Tb3+,Eu3+, has verified through spectra fluorescence decay dynamics. results mean that might potential applications as emitting for white LEDs.
rsc.org
sci-hub.se 参考文章(46)
Zhendong Hao, Jiahua Zhang, Xia Zhang, Xiaoyuan Sun, Yongshi Luo, Shaozhe Lu, Xiao-jun Wang, White light emitting diode by using α-Ca2P2O7:Eu2+, Mn2+ phosphor Applied Physics Letters. ,vol. 90, pp. 261113- ,(2007) , 10.1063/1.2752725
Yu-Ho Won, Ho Seong Jang, Won Bin Im, Duk Young Jeon, Jeong Soo Lee, Tunable full-color-emitting La0.827Al11.9O19.09:Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes Applied Physics Letters. ,vol. 89, pp. 231909- ,(2006) , 10.1063/1.2398887
Chongfeng Guo, Jie Yu, Xu Ding, Ming Li, Zhaoyu Ren, Jintao Bai, A Dual-Emission Phosphor LiCaBO3 : Ce3 + , Mn2 + with Energy Transfer for Near-UV LEDs Journal of The Electrochemical Society. ,vol. 158, ,(2011) , 10.1149/1.3526319
Xinguo Zhang, Menglian Gong, Single-phased white-light-emitting NaCaBO3:Ce3+,Tb3+,Mn2+ phosphors for LED applications Dalton Transactions. ,vol. 43, pp. 2465- 2472 ,(2014) , 10.1039/C3DT52328D
Maria Wierzbicka-Wieczorek, Uwe Kolitsch, Ekkehart Tillmanns, Synthesis and structural study of five new trisilicates, BaREE2Si3O10 (REE = Gd, Er, Yb, Sc) and SrY2Si3O10, including a review on the geometry of the Si3O10 unit European Journal of Mineralogy. ,vol. 22, pp. 245- 258 ,(2010) , 10.1127/0935-1221/2010/0022-1969
R. Reisfeld, N. Lieblich-Soffer, Energy transfer from UO22+ to Sm3+ in phosphate glass Journal of Solid State Chemistry. ,vol. 28, pp. 391- 395 ,(1979) , 10.1016/0022-4596(79)90090-2
Wei-Ren Liu, Chien-Hao Huang, Chiao-Wen Yeh, Yi-Chen Chiu, Yao-Tsung Yeh, Ru-Shi Liu, Single-phased white-light-emitting KCaGd(PO4)2:Eu2+,Tb3+,Mn2+ phosphors for LED applications RSC Advances. ,vol. 3, pp. 9023- 9028 ,(2013) , 10.1039/C3RA40471D
Rong-Jun Xie, Naoto Hirosaki, Takashi Takeda, Wide Color Gamut Backlight for Liquid Crystal Displays Using Three-Band Phosphor-Converted White Light-Emitting Diodes Applied Physics Express. ,vol. 2, pp. 022401- ,(2009) , 10.1143/APEX.2.022401
Y. Q. Li, N. Hirosaki, R. J. Xie, T. Takeda, M. Mitomo, Yellow-Orange-Emitting CaAlSiN3:Ce3+ Phosphor: Structure, Photoluminescence, and Application in White LEDs Chemistry of Materials. ,vol. 20, pp. 6704- 6714 ,(2008) , 10.1021/CM801669X
Ge Zhu, Shuangyu Xin, Yan Wen, Qian Wang, Meidan Que, Yuhua Wang, Warm white light generation from a single phased phosphor Sr10[(PO4)5.5(BO4)0.5](BO2):Eu2+, Mn2+, Tb3+ for light emitting diodes RSC Advances. ,vol. 3, pp. 9311- 9318 ,(2013) , 10.1039/C3RA00040K