The preparation and reactivity of metal-containing monomers. 54. Thermolysis of the acrylamide monomer [Co(CH2=CHCONH2)4(H2O)2](NO3)2

摘要: The kinetics and pathways of thermolysis the Co(II) complex with acrylamide, [Co(CH2=CHCONH2)4(H2O)2](NO3)2 (1) were studied. rate gas evolution is satisfactorily approximated by a first-order equation autocatalysis. composition gaseous solid products 1 was studied IR spectroscopy, mass spectrometry, electronic microscopy. Thermal transformations acrylamide include three macro stages: dehydration, polymerization dehydrated monomer, thermooxidative destruction resulting polymer.