Supported catalysts from polymerizable transition metal complexes

摘要: Abstract This review covers the last 12 years of research on synthesis and use heterogeneous catalysts obtained by co-polymerization suitable metal containing monomers (MCM). The catalytic applications these supported complexes are subdivided into three areas. Hydrogenation alkenes functionalized olefins covered first. Oxidation several substrates such as olefins, sulfides, alcohols, aldehydes then considered. Of particular interest in this framework is chiral salen for stereoselective epoxidation hindered olefins. Alkene alkyne polymerizations, Heck Heck-type reactions, allylic alkylation, Michael additions discussed field carboncarbon bond forming reactions. A common factor emerging from survey application molecularly imprinted polymers to be used or catalyst supports.