Effect of Deposition Temperature on Structural and Electrical Properties of Ga-Doped ZnO for Transparent Electrode of Thin Film Solar Cells

作者: Chang-Sik Son

DOI: 10.3740/MRSK.2011.21.3.144

关键词:

摘要: We have investigated the structural and electrical properties of Ga-doped ZnO (GZO) thin films deposited by anRF magnetron sputtering at various RF powers from 50 to 90W. All GZO are grown as a hexagonal wurtzitephase with highly c-axis preferred parameters. The strongly related power. Thegrain size increases power since columnar growth film is enhanced an elevated RFpower. This result means that crystallinity improved increases. resistivity rapidlydecreases up 70W saturates In contrast, electron concentration increasesas shows lowest 2.2×10−4Ωcmand highest 1.7×1021cm−3 mobility increasessince grain boundary scattering decreases due reduced density high Thetransmittance in visible range above 90%. feasible transparent electrode for application asa solar cells.

参考文章(15)
J.P. Wiff, Y. Kinemuchi, K. Watari, Hall mobilities of Al- and Ga-doped ZnO polycrystals Materials Letters. ,vol. 63, pp. 2470- 2472 ,(2009) , 10.1016/J.MATLET.2009.08.036
Bernard Dennis Cullity, Elements of X-ray diffraction ,(1956)
Hisashi Kaga, Yoshiaki Kinemuchi, Huseyin Yilmaz, Koji Watari, Hiromi Nakano, Hiroshi Nakano, Satoshi Tanaka, Atsushi Makiya, Zenji Kato, Keizo Uematsu, Orientation dependence of transport property and microstructural characterization of Al-doped ZnO ceramics Acta Materialia. ,vol. 55, pp. 4753- 4757 ,(2007) , 10.1016/J.ACTAMAT.2007.04.046
Y. Matsumoto, G. Hirata, H. Takakura, H. Okamoto, Y. Hamakawa, A new type of high efficiency with a low‐cost solar cell having the structure of a μc‐SiC/polycrystalline silicon heterojunction Journal of Applied Physics. ,vol. 67, pp. 6538- 6543 ,(1990) , 10.1063/1.345131
A. Hultåker, C.G. Granqvist, Transparent and conducting ITO films: new developments and applications Thin Solid Films. ,vol. 411, pp. 1- 5 ,(2002) , 10.1016/S0040-6090(02)00163-3
A. Martı́n, J.P. Espinós, A. Justo, J.P. Holgado, F. Yubero, A.R. González-Elipe, Preparation of transparent and conductive Al-doped ZnO thin films by ECR plasma enhanced CVD Surface & Coatings Technology. ,vol. 151, pp. 289- 293 ,(2002) , 10.1016/S0257-8972(01)01609-7
K. Vanheusden, C. H. Seager, W. L. Warren, D. R. Tallant, J. A. Voigt, Correlation between photoluminescence and oxygen vacancies in ZnO phosphors Applied Physics Letters. ,vol. 68, pp. 403- 405 ,(1996) , 10.1063/1.116699
Seung Wook Shin, Kyu Ung Sim, Jong-Ha Moon, Jin Hyeok Kim, The effect of processing parameters on the properties of Ga-doped ZnO thin films by RF magnetron sputtering Current Applied Physics. ,vol. 10, ,(2010) , 10.1016/J.CAP.2009.11.060
R.J. Hong, X. Jiang, B. Szyszka, V. Sittinger, A. Pflug, Studies on ZnO:Al thin films deposited by in-line reactive mid-frequency magnetron sputtering Applied Surface Science. ,vol. 207, pp. 341- 350 ,(2003) , 10.1016/S0169-4332(02)01525-8
Byeong-Guk Kim, Jeong-Yeon Kim, Byoung-Jin Oh, Dong-Gun Lim, Jae-Hwan Park, Duck-Hyun Woo, Soon-Yong Kweon, 산소플라즈마 전처리된 Polyethylene Naphthalate 기판 위에 증착된 ZnO:Ga 투명전도막의 특성 Korean Journal of Materials Research. ,vol. 20, pp. 175- 180 ,(2010) , 10.3740/MRSK.2010.20.4.175