Multiple Tandem Catalysis: Facile Cycling between Hydrogenation and Metathesis Chemistry

作者: Samantha D. Drouin , Fojan Zamanian , Deryn E. Fogg

DOI: 10.1021/OM010747D

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摘要: Tandem ROMP−hydrogenation via a single Ru precursor permits catalytic reduction of ROMP polymers under exceptionally mild, homogeneous conditions (1 atm H2, 60 °C). Repeated catalyst cycling between metathesis and hydrogenation chemistry is effected in one-pot procedure.

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