Highly Organized Polyolefin Structures

作者: Kenneth Boone Wagener , Travis W. Baughman

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摘要: A method of preparing periodic, semi-periodic, or semi-random polyethylene-co-acrylic acid polyethylene-co-methacrylic involves polymerizing 1-alkoxyalkyl ester substituted α,Ω-dienes, and/or cycloalkenes via olefin metathesis reactions followed by hydrogenation the alkylene units and subsequently hydrolyzed to desired acid. The can then be converted ionomers exchange with a monomeric carboxylate salt.

参考文章(3)
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John E. Schwendeman, Kenneth B. Wagener, Modeling Ethylene/Methyl Methacrylate and Ethylene/Methacrylic Acid Copolymers Using Acyclic Diene Metathesis Chemistry Macromolecules. ,vol. 37, pp. 4031- 4037 ,(2004) , 10.1021/MA0304574
Enock Berluche, Donald N. Schulz, Lisa Saunders Baugh, Stephen E. Lehman, Kenneth B. Wagener, Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof ,(2004)