作者: V. D. Rusanov , A. A. Fridman , G. V. Sholin
DOI: 10.1007/978-3-642-48615-9_10
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摘要: The intense progress in plasmachemistry, laser chemistry, and other branches of nonequilibrium chemistry has attracted significant attention to investigations the vibrational kinetics chemical reactions polyatomic molecules [10.1–4]. However, level understanding relaxation processes for is still noticeably lower than diatomic ones [10.5,6]. Detailed description highly excited states meets with obstacles due strong interaction various types oscillations, which, leads both complication energy spectrum difficulties calculating transition probabilities [10.6–8].