Vibrational Relaxation Times in Gases (Three‐Dimensional Treatment)
作者： Robert N. Schwartz , Karl F. Herzfeld
DOI: 10.1063/1.1740190
关键词: Range (particle radiation) 、 Atomic physics 、 Chemistry 、 Classical mechanics 、 Exponential function 、 Viscosity 、 Vibrational energy relaxation 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: The calculations previously made by Schwartz, Slawsky, and Herzfeld are extended to three dimensions. As before, an exponential repulsion is fitted the Lennard‐Jones potential, with constants found from viscosity data. While transition probability determined directly short range forces, attractive forces effect of centrifugal quasi‐potential modify effective velocity colliding molecules. agreement experiment fairly good, although high up on curve (O2,N2) 6—12 seems be not quite steep enough.
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