The reaction dynamics of sodium with ozone
作者： Michael H. Covinsky , Arthur G. Suits , H. Floyd Davis , Yuan T. Lee
DOI: 10.1063/1.463089
关键词:
摘要: The reaction of sodium atoms (Na) with ozone (O3) has been studied using crossed molecular beams at a collision energy 18 kcal/mole. only product observed was NaO. occurs via an electron‐transfer mechanism that yields NaO which is forward scattered respect to the beam. translational distribution peaks near stripping limit but extends out maximum allowed by conservation. fragmentation ratio upon electron bombardment ionization I(NaO+)/[I(NaO+)+I(Na+)] as function measured for 200 V.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(31)
R Abouaf, R Paineau, F Fiquet-Fayard, Dissociative attachment in NO2 and CO2 Journal of Physics B. ,vol. 9, pp. 303- 314 ,(1976) , 10.1088/0022-3700/9/2/017
R. K. Curran, Negative Ion Formation in Ozone Journal of Chemical Physics. ,vol. 35, pp. 1849- 1851 ,(1961) , 10.1063/1.1732155
Alan Carrington, Iain R. McNab, Christine A. Montgomerie, Laser excitation and electric field dissociation spectroscopy of the HD+ ion Chemical Physics Letters. ,vol. 151, pp. 258- 262 ,(1988) , 10.1016/0009-2614(88)85285-0
David Husain, John M. C. Plane, Kinetic investigation of the reaction between Na + O2+ M by time-resolved atomic resonance absorption spectroscopy Journal of the Chemical Society, Faraday Transactions. ,vol. 78, pp. 163- 178 ,(1982) , 10.1039/F29827800163
R. R. Herm, D. R. Herschbach, Molecular Beam Kinetics: Reactions of Alkali Atoms with NO2and CH3NO2 The Journal of Chemical Physics. ,vol. 52, pp. 5783- 5792 ,(1970) , 10.1063/1.1672860
S. Chapman, Notes on Atmospheric Sodium. The Astrophysical Journal. ,vol. 90, pp. 309- ,(1939) , 10.1086/144109
J.R. Woodward, J.S. Hayden, J.L. Gole, Formation and characterization of a low-lying electronic state of the alkali monoxides LiO…CsO in the red and near infrared Chemical Physics. ,vol. 134, pp. 395- 419 ,(1989) , 10.1016/0301-0104(89)87171-X
D. R. Bates, P. C. Ojha, Excitation of the Na D-doublet of the nightglow Nature. ,vol. 286, pp. 790- 791 ,(1980) , 10.1038/286790A0
DonaldM. Hunten, Spectroscopic studies of the twilight airglow Space Science Reviews. ,vol. 6, pp. 493- 573 ,(1967) , 10.1007/BF00173704
D. R. Worsnop, M. S. Zahniser, C. E. Kolb, Low-temperature absolute rate constants for the reaction of atomic sodium with ozone and nitrous oxide The Journal of Physical Chemistry. ,vol. 95, pp. 3960- 3964 ,(1991) , 10.1021/J100163A014