Transient operation of a catalytic liquid–liquid plug flow reactor for kinetics measurements

摘要: Abstract A centrifugal partition chromatograph (CPC) was used as a liquid–liquid catalytic reactor for the isomerisation of hexen-3-ol into ethylpropylketone with water soluble rhodium catalyst. Global mass transfer coefficients were measured and shown to depend on both nature solute flow rate. Liquid–liquid isotherms also determined CPC using elution chromatography. Finally, model derived account experimental results obtained under stationary transient (pulse) conditions. parameter sensitivity evaluation is presented.