A simplified all-polymer flexible electrochromic device

作者: David Mecerreyes , Rebeca Marcilla , Estibalitz Ochoteco , Hans Grande , Jose A. Pomposo

DOI: 10.1016/J.ELECTACTA.2004.03.032

关键词:

摘要: New all-polymeric simplified electrochromic devices have been prepared based in an intrinsically conductive polymer, poly (ethylene dioxythiophene)(PEDOT). In these devices PEDOT acts simultaneously as electrochromic layer and current collector layer simplifying the construction of the classic devices from seven to five layers. The device presents a chromatic contrast in all the visible range with a maximum at 650nm (ΔT= 0.15) between 0 and 3V. Representative bleaching and coloring times are 20 and 16s, respectively, for 5 cm× …

参考文章(17)
Claes-Göran Granqvist, Handbook of inorganic electrochromic materials ,(1995)
L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, J. R. Reynolds, Poly(3,4‐ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future Advanced Materials. ,vol. 12, pp. 481- 494 ,(2000) , 10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO;2-C
J.S.E. M. Svensson, C. G. Granqvist, Electrochromic Coatings For "Smart Windows" Optical Materials Technology for Energy Efficiency and Solar Energy Conversion III. ,vol. 0502, pp. 30- 37 ,(1984) , 10.1117/12.944782
Qibing Pei, Guido Zuccarello, Markus Ahlskog, Olle Inganäs, Electrochromic and highly stable poly(3,4-ethylenedioxythiophene) switches between opaque blue-black and transparent sky blue Polymer. ,vol. 35, pp. 1347- 1351 ,(1994) , 10.1016/0032-3861(94)90332-8
Barry C. Thompson, Philippe Schottland, Kyukwan Zong, John R. Reynolds, In situ colorimetric analysis of electrochromic polymers and devices Chemistry of Materials. ,vol. 12, pp. 1563- 1571 ,(2000) , 10.1021/CM000097O
Fernando Fungo, Samson A. Jenekhe, Allen J. Bard, Plastic Electrochromic Devices: Electrochemical Characterization and Device Properties of a Phenothiazine-Phenylquinoline Donor−Acceptor Polymer Chemistry of Materials. ,vol. 15, pp. 1264- 1272 ,(2003) , 10.1021/CM0210445
A.A. Argun, A. Cirpan, J.R. Reynolds, The First Truly All‐Polymer Electrochromic Devices Advanced Materials. ,vol. 15, pp. 1338- 1341 ,(2003) , 10.1002/ADMA.200305038
David S. Ginley, Clark Bright, Transparent Conducting Oxides Mrs Bulletin. ,vol. 25, pp. 15- 18 ,(2000) , 10.1557/MRS2000.256
D. DeLongchamp, P. T. Hammond, Layer-by-layer assembly of PEDOT/polyaniline electrochromic devices Advanced Materials. ,vol. 13, pp. 1455- 1459 ,(2001) , 10.1002/1521-4095(200110)13:19<1455::AID-ADMA1455>3.0.CO;2-7