Coating Formation on Ti-6Al-4V Alloy by Micro Arc Oxidation in Molten Salt.

作者: Alexander Sobolev , Israel Wolicki , Alexey Kossenko , Michael Zinigrad , Konstantin Borodianskiy

DOI: 10.3390/MA11091611

关键词:

摘要: Micro Arc Oxidation (MAO) is an electrochemical surface treatment process to produce oxide protective coatings on some metals. MAO usually conducted in aqueous electrolyte, which requires intensive bath cooling and leads the formation of a coating containing impurities that originate electrolyte. In current work, we applied alternative ceramic Ti-6Al-4V alloy using molten nitrate salt at temperature 280 °C. The obtained morphology, chemical phase composition, corrosion resistance were investigated described. results showed 2.5 µm was formed after 10 min treatment, titanium titanium‒aluminum intermetallic phases. Morphological examination indicated free cracks contains round, homogeneously distributed pores. Corrosion testing Ti 20 times more resistive than untreated alloy.

参考文章(31)
Alexey Kossenko, Michael Zinigrad, A universal electrolyte for the plasma electrolytic oxidation of aluminum and magnesium alloys Materials & Design. ,vol. 88, pp. 302- 309 ,(2015) , 10.1016/J.MATDES.2015.08.071
S. Aliasghari, P. Skeldon, G.E. Thompson, Plasma electrolytic oxidation of titanium in a phosphate/silicate electrolyte and tribological performance of the coatings Applied Surface Science. ,vol. 316, pp. 463- 476 ,(2014) , 10.1016/J.APSUSC.2014.08.037
A.L. Yerokhin, X. Nie, A. Leyland, A. Matthews, S.J. Dowey, Plasma electrolysis for surface engineering Surface and Coatings Technology. ,vol. 122, pp. 73- 93 ,(1999) , 10.1016/S0257-8972(99)00441-7
M. Geetha, A.K. Singh, R. Asokamani, A.K. Gogia, Ti based biomaterials, the ultimate choice for orthopaedic implants – A review Progress in Materials Science. ,vol. 54, pp. 397- 425 ,(2009) , 10.1016/J.PMATSCI.2008.06.004
A.L. Yerokhin, X. Nie, A. Leyland, A. Matthews, Characterisation of oxide films produced by plasma electrolytic oxidation of a Ti–6Al–4V alloy Surface & Coatings Technology. ,vol. 130, pp. 195- 206 ,(2000) , 10.1016/S0257-8972(00)00719-2
Paweł E. Tomaszewski, Structural phase transitions in crystals. I. Database Phase Transitions. ,vol. 38, pp. 127- 220 ,(1992) , 10.1080/01411599208222899
J.M. Wheeler, C.A. Collier, J.M. Paillard, J.A. Curran, Evaluation of micromechanical behaviour of plasma electrolytic oxidation (PEO) coatings on Ti–6Al–4V Surface & Coatings Technology. ,vol. 204, pp. 3399- 3409 ,(2010) , 10.1016/J.SURFCOAT.2010.04.006
Yaming Wang, Tingquan Lei, Bailing Jiang, Lixin Guo, Growth, microstructure and mechanical properties of microarc oxidation coatings on titanium alloy in phosphate-containing solution Applied Surface Science. ,vol. 233, pp. 258- 267 ,(2004) , 10.1016/J.APSUSC.2004.03.231
H. Habazaki, S. Tsunekawa, E. Tsuji, T. Nakayama, Formation and characterization of wear-resistant PEO coatings formed on β-titanium alloy at different electrolyte temperatures Applied Surface Science. ,vol. 259, pp. 711- 718 ,(2012) , 10.1016/J.APSUSC.2012.07.104