The influence of deuterium exposures on subsequent outgassing rate of an UHV system

作者: Vincenc Nemanič , Bojan Zajec

DOI: 10.1016/J.VACUUM.2006.07.017

关键词:

摘要: Abstract The accuracy of results in experiments where a well-processed UHV system is exposed to hydrogen depends on the absorption rate and kinetics subsequent spontaneous release from itself. In date, sensitivity required detect very low rates has been achieved only when tritium used as tracer gas. Unfortunately, tritiated water surface prevails among released gas species which not expected for well-outgassed surfaces. present studies, behaviour at 303 K during three deuterium exposures duration 92 72 h an initial pressure 1 mbar was explored. decrease constant whole these periods monitored by non-ionizing vacuum gauges. It corresponded effective sticking probability order 1 × 10 - 12 resulted 5 14 D atoms/cm2. were observed several days starting immediately after had pumped system. Initially, exceeded background outgassing more than orders magnitude. These demonstrate that extremely high can be with precise measuring technique otherwise attributed exclusively scintillation methods.

参考文章(19)
A. Pisarev, V. Shestakov, R. Hayakawa, Y. Hatano, K. Watanabe, Gas-driven hydrogen permeation in the surface-limited regime Journal of Nuclear Materials. ,vol. 320, pp. 214- 222 ,(2003) , 10.1016/S0022-3115(03)00110-7
A. M. Horgan, I. Dalins, Adsorption of Hydrogen, Carbon Monoxide, and Oxygen on Vacuum Degassed Stainless Steel 304 at 20 °C Journal of Vacuum Science and Technology. ,vol. 10, pp. 559- 561 ,(1973) , 10.1116/1.1318063
P. L. Andrew, A. A. Haasz, Models for hydrogen permeation in metals Journal of Applied Physics. ,vol. 72, pp. 2749- 2757 ,(1992) , 10.1063/1.351526
P. A. Redhead, Effects of readsorption on outgassing rate measurements Journal of Vacuum Science and Technology. ,vol. 14, pp. 2599- 2609 ,(1996) , 10.1116/1.579987
T. Hirabayashi, M. Saeki, Sorption of gaseous tritium on the surface of type 316 stainless steel Journal of Nuclear Materials. ,vol. 120, pp. 309- 315 ,(1984) , 10.1016/0022-3115(84)90069-2
A. Perevezentsev, K. Watanabe, M. Matsuyama, Y. Torikai, Screen Test of Tritium Recovery from Stainless Steel Type 316 Fusion Science and Technology. ,vol. 41, pp. 706- 710 ,(2002) , 10.13182/FST41-706
A. Berman, J. K. Fremerey, Precision calibration of a static pressure divider by means of a spinning rotor gauge Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. ,vol. 5, pp. 2436- 2439 ,(1987) , 10.1116/1.574865
S. Wright, J. F. Skelly, A. Hodgson, Energy disposal during desorption of D2 from the surface and subsurface region of Ni(111) Faraday Discussions. ,vol. 117, pp. 133- 146 ,(2000) , 10.1039/B004010J