Amine-Rich Nitrogen-Doped Carbon Nanodots as a Platform for Self-Enhancing Electrochemiluminescence

作者: Serena Carrara , Francesca Arcudi , Maurizio Prato , Luisa De Cola

DOI: 10.1002/ANIE.201611879

关键词:

摘要: Amine-rich nitrogen-doped carbon nanodots (NCNDs) have been successfully used as co-reactant in electrochemiluminescence (ECL) processes. Primary or tertiary amino groups on NCNDs studied sites for Ru(bpy)32+ ECL, showing their eligibility powerful alternatives to tripropylamine (TPrA). We also report the synthesis and ECL behavior of a new covalently linked hybrid . Notably, act both carrier labels generation. As result, shows higher emission compared combination individual components, suggesting self-enhancing ruthenium complex due an intramolecular electron transfer process.

参考文章(38)
Frédéric Kanoufi, Yanbing Zu, Allen J. Bard, Homogeneous Oxidation of Trialkylamines by Metal Complexes and Its Impact on Electrogenerated Chemiluminescence in the Trialkylamine/Ru(bpy)32+ System Journal of Physical Chemistry B. ,vol. 105, pp. 210- 216 ,(2001) , 10.1021/JP002880+
Prathik Roy, Po-Cheng Chen, Arun Prakash Periasamy, Ya-Na Chen, Huan-Tsung Chang, Photoluminescent carbon nanodots: synthesis, physicochemical properties and analytical applications Materials Today. ,vol. 18, pp. 447- 458 ,(2015) , 10.1016/J.MATTOD.2015.04.005
Zhongyuan Liu, Wenjing Qi, Guobao Xu, Recent advances in electrochemiluminescence Chemical Society Reviews. ,vol. 44, pp. 3117- 3142 ,(2015) , 10.1039/C5CS00086F
Nurhan E. Tokel-Takvoryan, Ronald E. Hemingway, Allen J. Bard, Electrogenerated chemiluminescence. XIII. Electrochemical and electrogenerated chemiluminescence studies of ruthenium chelates Journal of the American Chemical Society. ,vol. 95, pp. 6582- 6589 ,(1973) , 10.1021/JA00801A011
Deniz. Ege, William G. Becker, Allen J. Bard, Electrogenerated chemiluminescent determination of Ru(bpy)3(2+) at low levels. Analytical Chemistry. ,vol. 56, pp. 2413- 2417 ,(1984) , 10.1021/AC00277A036
Sheng-Tao Yang, Li Cao, Pengju G. Luo, Fushen Lu, Xin Wang, Haifang Wang, Mohammed J. Meziani, Yuanfang Liu, Gang Qi, Ya-Ping Sun, Carbon dots for optical imaging in vivo. Journal of the American Chemical Society. ,vol. 131, pp. 11308- 11309 ,(2009) , 10.1021/JA904843X
Wujian Miao, Electrogenerated Chemiluminescence and Its Biorelated Applications Chemical Reviews. ,vol. 108, pp. 2506- 2553 ,(2008) , 10.1021/CR068083A
Israel Rubinstein, Allen J. Bard, Electrogenerated chemiluminescence. 37. Aqueous ecl systems based on tris(2,2'-bipyridine)ruthenium(2+) and oxalate or organic acids Journal of the American Chemical Society. ,vol. 103, pp. 512- 516 ,(1981) , 10.1021/JA00393A006