Carbon - clay composite obtained from the decomposition of cellulose nanocrystals on the surface of expanded vermiculite
作者： João P. de Mesquita , Leonardo S. Reis , Aluir D. Purceno , Claudio L. Donnici , Rochel M. Lago
DOI: 10.1002/JCTB.3952
关键词:
摘要: Abstract BACKGROUND: Cellulose nanocrystals (CNCs) are highly crystalline rod-shaped nanoparticles, which can be obtained fromdifferent cellulose sources through acid hydrolysis. The nanometer size, morphology, facile preparation, and relatively low costmake these nanomaterials a new interesting candidate as precursor of biomass-based carbon nanostructures.RESULTS: were dispersed on the surface in internal layers expanded vermiculite clay(EV) thermally decomposed to form coating. SEM/EDS, TEM, IR, Raman, TGA BET techniques showed thepresence nanostructures formed by films, agglomerates spherical particles composed amorphous graphiticcarbon throughout EV surface.CONCLUSION: modified with produced strongly hydrophobic porous material that canpotentially used absorb oil spilling accidents emerging contaminants water. c 2012 Society Chemical Industry Supportinginformationmaybefoundintheonlineversionofthisarticle.
sci-hub.se 参考文章(34)
Honória F. Gorgulho, João P. Mesquita, Filomena Gonçalves, Manuel Fernando R. Pereira, José L. Figueiredo, Characterization of the surface chemistry of carbon materials by potentiometric titrations and temperature-programmed desorption Carbon. ,vol. 46, pp. 1544- 1555 ,(2008) , 10.1016/J.CARBON.2008.06.045
Youssef Habibi, Lucian A. Lucia, Orlando J. Rojas, Cellulose nanocrystals: chemistry, self-assembly, and applications. Chemical Reviews. ,vol. 110, pp. 3479- 3500 ,(2010) , 10.1021/CR900339W
Maren Roman, William T. Winter, Effect of sulfate groups from sulfuric acid hydrolysis on the thermal degradation behavior of bacterial cellulose. Biomacromolecules. ,vol. 5, pp. 1671- 1677 ,(2004) , 10.1021/BM034519+
Samira Elazzouzi-Hafraoui, Yoshiharu Nishiyama, Jean-Luc Putaux, Laurent Heux, Frédéric Dubreuil, Cyrille Rochas, The Shape and Size Distribution of Crystalline Nanoparticles Prepared by Acid Hydrolysis of Native Cellulose Biomacromolecules. ,vol. 9, pp. 57- 65 ,(2008) , 10.1021/BM700769P
My Ahmed Said Azizi Samir, Fannie Alloin, Alain Dufresne, None, Review of Recent Research into Cellulosic Whiskers, Their Properties and Their Application in Nanocomposite Field Biomacromolecules. ,vol. 6, pp. 612- 626 ,(2005) , 10.1021/BM0493685
Flávia C.C. Moura, Rochel M. Lago, Catalytic growth of carbon nanotubes and nanofibers on vermiculite to produce floatable hydrophobic “nanosponges” for oil spill remediation Applied Catalysis B-environmental. ,vol. 90, pp. 436- 440 ,(2009) , 10.1016/J.APCATB.2009.04.003
Stephanie Beck-Candanedo, Maren Roman, Derek G. Gray, Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. Biomacromolecules. ,vol. 6, pp. 1048- 1054 ,(2005) , 10.1021/BM049300P
Susheel Kalia, Alain Dufresne, Bibin Mathew Cherian, Balbir Singh Kaith, Luc Avérous, James Njuguna, Elias Nassiopoulos, None, Cellulose-Based Bio- and Nanocomposites: A Review International Journal of Polymer Science. ,vol. 2011, pp. 35- ,(2011) , 10.1155/2011/837875
Maria D. Sanchez-Garcia, Jose M. Lagaron, On the use of plant cellulose nanowhiskers to enhance the barrier properties of polylactic acid Cellulose. ,vol. 17, pp. 987- 1004 ,(2010) , 10.1007/S10570-010-9430-X
Y. El Mouzdahir, A. Elmchaouri, R. Mahboub, A. Gil, S.A. Korili, Synthesis of nano-layered vermiculite of low density by thermal treatment Powder Technology. ,vol. 189, pp. 2- 5 ,(2009) , 10.1016/J.POWTEC.2008.06.013