Self-assembly of nanosize coordination cages on si(100) surfaces.
作者： Marco Busi , Marco Laurenti , Guglielmo G. Condorelli , Alessandro Motta , Maria Favazza
关键词:
摘要: Bottom-up fabrication of 3D organic nanostructures on Si(100) surfaces has been achieved by a two-step procedure. Tetradentate cavitand 1 was grafted the Si surface together with 1-octene (Oct) as spatial spectator photochemical hydrosilylation. Ligand exchange between and self-assembled homocage 2, derived from 5 bearing fluorescence marker, led to formation coordination cages Si(100). Formation, quantification, distribution nanoscale molecular containers silicon assessed using three complementary analytical techniques (AFM, XPS, fluorescence) validated control experiments cavitand-free surfaces. Interestingly, pyrene at approximately 4 nm above can be clearly observed.
sci-hub.se 参考文章(38)
Donald J Cram, Jane M Cram, Container Molecules and their Guests ,(1994)
AB Sieval, AL Demirel, JWM Nissink, MR Linford, JH Van der Maas, WH De Jeu, H Zuilhof, EJR Sudhölter, None, Highly Stable Si−C Linked Functionalized Monolayers on the Silicon (100) Surface Langmuir. ,vol. 14, pp. 1759- 1768 ,(1998) , 10.1021/LA971139Z
Roberta Pinalli, Veronica Cristini, Valerio Sottili, Silvano Geremia, Mara Campagnolo, Andrea Caneschi, Enrico Dalcanale, Cavitand-Based Nanoscale Coordination Cages Journal of the American Chemical Society. ,vol. 126, pp. 6516- 6517 ,(2004) , 10.1021/JA038694+
C. H. Pfaff, Just. Liebig, Ueber die Zusammensetzung des Caffeins European Journal of Organic Chemistry. ,vol. 1, pp. 17- 20 ,(1832) , 10.1002/JLAC.18320010104
Guglielmo G. Condorelli, Alessandro Motta, Maria Favazza, Ignazio L. Fragalà, Marco Busi, Edoardo Menozzi, Enrico Dalcanale, Luigi Cristofolini, Grafting Cavitands on the Si(100) Surface Langmuir. ,vol. 22, pp. 11126- 11133 ,(2006) , 10.1021/LA060682P
Jillian M. Buriak, Organometallic Chemistry on Silicon and Germanium Surfaces Chemical Reviews. ,vol. 102, pp. 1271- 1308 ,(2002) , 10.1021/CR000064S
Matthew R. Linford, Paul Fenter, Peter M. Eisenberger, Christopher E. D. Chidsey, Alkyl Monolayers on Silicon Prepared from 1-Alkenes and Hydrogen-Terminated Silicon Journal of the American Chemical Society. ,vol. 117, pp. 3145- 3155 ,(1995) , 10.1021/JA00116A019
Pascal Anger, Palash Bharadwaj, Lukas Novotny, Enhancement and quenching of single-molecule fluorescence. Physical Review Letters. ,vol. 96, pp. 113002- ,(2006) , 10.1103/PHYSREVLETT.96.113002
A. L. Barra, A. Caneschi, A. Cornia, F. Fabrizi de Biani, D. Gatteschi, C. Sangregorio, R. Sessoli, L. Sorace, Single-Molecule Magnet Behavior of a Tetranuclear Iron(III) Complex. The Origin of Slow Magnetic Relaxation in Iron(III) Clusters Journal of the American Chemical Society. ,vol. 121, pp. 5302- 5310 ,(1999) , 10.1021/JA9818755
Qiao-Yu Sun, Louis CPM de Smet, Barend van Lagen, Marcel Giesbers, Peter C Thüne, Johan van Engelenburg, Frits A de Wolf, Han Zuilhof, Ernst JR Sudhölter, None, Covalently attached monolayers on crystalline hydrogen-terminated silicon: extremely mild attachment by visible light. Journal of the American Chemical Society. ,vol. 127, pp. 2514- 2523 ,(2005) , 10.1021/JA045359S