Equilibrium Constant for Boron Isotope Exchange between BF3 and BF3·O (CH3)2
作者： A. A. Palko , G. M. Begun , L. Landau
DOI: 10.1063/1.1701372
关键词:
摘要: The isotopic equilibrium constant for boron exchange between BF3 and BF3·O (CH3)2 has been measured at −8°, 4°, 22°C. values are compared with calculated from infrared Raman spectral data. physical basis isotope fractionation in systems of this type is discussed.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(15)
Alvin H. Nielsen, Infrared Spectrum of σ2 for B10F3 and B11F3 The Journal of Chemical Physics. ,vol. 22, pp. 659- 664 ,(1954) , 10.1063/1.1740143
Harold C. Urey, D. Rittenberg, Some Thermodynamic Properties of the H1H2, H2H2Molecules and Compounds Containing the H2Atom The Journal of Chemical Physics. ,vol. 1, pp. 137- 143 ,(1933) , 10.1063/1.1749265
A. A. Palko, R. M. Healy, L. Landau, Separation of Boron Isotopes. II. The BF3 Anisole System Journal of Chemical Physics. ,vol. 28, pp. 214- 217 ,(1958) , 10.1063/1.1744095
A. L. Conn, J. E. Wolf, Large-Scale Separation of Boron Isotopes Industrial & Engineering Chemistry. ,vol. 50, pp. 1231- 1234 ,(1958) , 10.1021/IE50585A024
A. A. Palko, J. S. Drury, W. E. Bull, Separation of Boron Isotopes. V. The Phenol‐BF3 System Journal of Chemical Physics. ,vol. 35, pp. 103- 105 ,(1961) , 10.1063/1.1731875
Jacob Bigeleisen, Maria Goeppert Mayer, Calculation of Equilibrium Constants for Isotopic Exchange Reactions The Journal of Chemical Physics. ,vol. 15, pp. 261- 267 ,(1947) , 10.1063/1.1746492
Jack Vanderryn, Infrared Spectrum of BF3 The Journal of Chemical Physics. ,vol. 30, pp. 331- 332 ,(1959) , 10.1063/1.1729915
G.M. Begun, W.H. Fletcher, A.A. Palko, Infrared and Raman spectra of the boron trifluoride-dimethyl ether complex Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 18, pp. 655- 665 ,(1962) , 10.1016/0371-1951(62)80070-8
Karl Erik O Holmberg, Separation of boron isotopes ,(1957)
Herbert C. Brown, Richard M. Adams, Studies in Stereochemistry. II. Steric Strains as a Factor in the Relative Stability of Some Etherates of Boron Fluoride Journal of the American Chemical Society. ,vol. 64, pp. 2557- 2563 ,(1942) , 10.1021/JA01263A009