Raman and Infrared Spectra of the10BF3and11BF3Complexes with Dimethyl Sulfide and the Isotopic Exchange of This Complex with BF3

作者: G. M. Begun , A. A. Palko

DOI: 10.1063/1.1712064

关键词:

摘要: The Raman and infrared spectra of liquid BF3·dimethyl sulfide have been recorded for both the 10B 11B compounds. Assignments observed bands made using analogies with those ether. isotopic data used to calculate theoretical equilibrium constants exchange between complex BF3. calculated values are compared published experimental values.

参考文章(8)
A. A. Palko, G. M. Begun, L. Landau, Equilibrium Constant for Boron Isotope Exchange between BF3 and BF3·O (CH3)2 Journal of Chemical Physics. ,vol. 37, pp. 552- 555 ,(1962) , 10.1063/1.1701372
J.R. Allkins, P.J. Hendra, The infra-red and Raman spectra of dimethyl sulphide, selenide and telluride Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 22, pp. 2075- 2081 ,(1966) , 10.1016/0371-1951(66)80056-5
A. A. Palko, J. S. Drury, Separation of Boron Isotopes. IV. The Methyl Sulfide‐BF3 System The Journal of Chemical Physics. ,vol. 33, pp. 779- 781 ,(1960) , 10.1063/1.1731260
A. E. Douglas, D. H. Rank, Determination of the depolarization factors of highly polarized Raman lines. Journal of the Optical Society of America. ,vol. 38, pp. 281- 287 ,(1948) , 10.1364/JOSA.38.000281
Jack Vanderryn, Infrared Spectrum of BF3 The Journal of Chemical Physics. ,vol. 30, pp. 331- 332 ,(1959) , 10.1063/1.1729915
G.M. Begun, W.H. Fletcher, A.A. Palko, Infrared and Raman spectra of the boron trifluoride-dimethyl ether complex Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 18, pp. 655- 665 ,(1962) , 10.1016/0371-1951(62)80070-8
S. H. Bauer, G. R. Finlay, A. W. Laubengayer, On the Structure of Dimethyl Ether-Boron Trifluoride Journal of the American Chemical Society. ,vol. 67, pp. 339- 341 ,(1945) , 10.1021/JA01218A503