Visible light-harvesting in covalently-linked porphyrin-cyanine dyes

作者: Jonathan S. Lindsey , Philip A. Brown , David A. Siesel

DOI: 10.1016/S0040-4020(01)85156-5

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摘要: Abstract We report the synthesis and properties of three members a new class photochemical model compounds containing covalently-linked porphyrin cyanine dye. In 1 2 dye absorbs in 450–570 nm region energy transfer occurs with 80% efficiency from to free base porphyrin. compound 3 650–780 The zinc-porphyrin-dyes exhibit both donor acceptor quenching only moderate yields transfer. This work is first step toward development an artificial phycobilisome.

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