Heteronuclear Magnetic Resonance Applications to Biological and Related Paramagnetic Molecules

作者: Joël Mispelter , Michel Momenteau , Jean-Marc Lhoste

DOI: 10.1007/978-1-4615-2886-9_6

关键词:

摘要: Nuclear magnetic resonance spectroscopy of paramagnetic molecules has proven to be a powerful tool in investigating the geometric and electronic structures biological and, more generally, chemical compounds incorporating metal ions. The perturbations due unpaired electrons are such that nuclei located near vicinity center exhibit unusual shifts relaxation rates which distinguish them from diamagnetic background.

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