Natural abundance 13C-NMR study of paramagnetic horse heart ferricytochrome c cyanide complex: Assignment of hyperfine shifted heme methyl carbon resonances
作者： Y. Yamamoto , N. Nanai , Y. Inoue , R. Chûjô
DOI: 10.1016/0006-291X(88)90588-8
关键词:
摘要: Abstract Hyperfine shifted heme methyl carbon resonances of paramagnetic horse heart ferricytochrome c cyanide complex (Cyt-c(CN)) have been observed for the first time in natural abundance 13C-NMR spectrum and assigned using 1H-13C heteronuclear chemical shift correlated spectroscopy (1H-13C COSY). Individual NMR signal assignment permits a direct comparison between hyperfine shifts attached proton which provides useful information on delocalization mechanism unpaired spin from π-conjugated system porphyrin ring into peripheral side chains.
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