Enhancement in the magnetic moment with Cr3+ doping and its effect on the magneto-structural properties of Ce0.1Y2.9Fe5O12

作者: S. R. Naik , A. V. Salker

DOI: 10.1039/C2CP41155E

关键词:

摘要: A change in the overall magnetic moment of Cr3+ doped cubic garnet ferrites prepared by modified sol–gel auto combustion method has been investigated. systematic Crystal Field Theory (CFT) approach is utilized towards understanding this variation moment. The malate glycolate precursor obtained autocombustion proves to be efficient monophasic preparation system. X-Ray Diffraction (XRD) confirms phase formation and purity. X-ray Photoelectron Spectroscopy (XPS) Raman spectroscopy have confirm valence states elements compounds. hyperfine field with doping revealed Mossbauer Spectroscopy. Vibrating Sample Magnetometer (VSM) employed probe properties composition temperature. decrease magnitude antiferromagnetic interaction at a d sites, inclusion site contribution L–S coupling from ions an increase resultant moment, significant finding investigation.

参考文章(35)
Y.F. Chen, K.T. Wu, Y.D. Yao, C.H. Peng, K.L. You, W.S. Tse, The influence of Fe concentration on Y3Al5-xFexO12 garnets Microelectronic Engineering. ,vol. 81, pp. 329- 335 ,(2005) , 10.1016/J.MEE.2005.03.028
Jian Xu, Xinde Bai, Yudian Fan, Wenliang Liu, Hongbin Bei, Studies on the corrosion behavior of yttrium-implanted zircaloy-4 Journal of Materials Science. ,vol. 35, pp. 6225- 6229 ,(2000) , 10.1023/A:1026745714887
Yahia Z. Hamada, Brandon Carlson, Joseph Dangberg, Interaction of Malate and Lactate with Chromium(III) and Iron(III) in Aqueous Solutions Synthesis and Reactivity in Inorganic and Metal-organic Chemistry. ,vol. 35, pp. 515- 522 ,(2005) , 10.1080/15533170500198887
Haitao Xu, Hua Yang, Effect of Chromium on Magnetic Properties of Y2.9Ce0.1Fe5-xCrxO12 Nanoparticles Materials and Manufacturing Processes. ,vol. 23, pp. 10- 13 ,(2007) , 10.1080/10426910701524279
V.D. Murumkar, K.B. Modi, K.M. Jadhav, G.K. Bichile, R.G. Kulkarni, Magnetic and electrical properties of aluminium and chromium co-substituted yttrium iron garnets Materials Letters. ,vol. 32, pp. 281- 285 ,(1997) , 10.1016/S0167-577X(97)00046-3
Lalitha Sirdeshmukh, K Krishna Kumar, S Bal Laxman, A Rama Krishna, G Sathaiah, Dielectric properties and electrical conduction in yttrium iron garnet (YIG) Bulletin of Materials Science. ,vol. 21, pp. 219- 226 ,(1998) , 10.1007/BF02744973