Observation of Nano-Particles in Silica/poly(HEMA) Hybrid by Electron Microscopy
作者： Dar-Jong Lin , Ching-Chung Chen , Cheng-Liang Chang , Yi-Che Su , Liao-Ping Cheng
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摘要: The sol–gel method was employed to prepare an inorganic–organic hybrid, silica/poly(HEMA). chemical structure of this material analyzed by means FTIR and solid 29Si-NMR. Using TEM low voltage FESEM imaging at high magnifications (e.g., 300 KX), the hybrid found comprise nano-particles whose sizes fall largely over range 20–30 nm.
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sci-hub.se 参考文章(8)
C.J. Brinker, Sol-gel science San Diego, CA (USA); Academic Press Inc.. ,(1990)
Sol-gel processing and applications Springer US. ,(1994) , 10.1007/978-1-4615-2570-7
Christine J. T. Landry, Bradley K. Coltrain, Michael R. Landry, John J. Fitzgerald, Victoria K. Long, Poly(vinyl acetate)/silica-filled materials: material properties of in situ vs fumed silica particles Macromolecules. ,vol. 26, pp. 3702- 3712 ,(1993) , 10.1021/MA00066A032
Francoise Surivet, Lam Thanh My, Jean Pierre Pascault, Pham Quang Tho, Organic-inorganic hybrid materials. 1. Hydrolysis and condensation mechanisms involved in alkoxysilane-terminated macromonomers Macromolecules. ,vol. 25, pp. 4309- 4320 ,(1992) , 10.1021/MA00043A011
Hao Hsin Huang, Bruce Orler, Garth L. Wilkes, Structure-property behavior of new hybrid materials incorporating oligomeric species into sol-gel glasses. 3. Effect of acid content, tetraethoxysilane content, and molecular weight of poly(dimethylsiloxane) Macromolecules. ,vol. 20, pp. 1322- 1330 ,(1987) , 10.1021/MA00172A026
P. Bosch, F. Del Monte, J. L. Mateo, D. Levy, Photopolymerization of hydroxyethylmethacrylate in the formation of organic–inorganic hybrid sol–gel matrices Journal of Polymer Science Part A. ,vol. 34, pp. 3289- 3296 ,(1996) , 10.1002/(SICI)1099-0518(19961130)34:16<3289::AID-POLA4>3.0.CO;2-P
Wen Zhou, Jian Hua Dong, Kun Yun Qiu, Yen Wei, Preparation and properties of poly(styrene-co-maleic anhydride)/silica hybrid materials by the in situ sol-gel process Journal of Polymer Science Part A. ,vol. 36, pp. 1607- 1613 ,(1998) , 10.1002/(SICI)1099-0518(19980730)36:10<1607::AID-POLA13>3.0.CO;2-K
P. Hajji, L. David, J. F. Gerard, J. P. Pascault, G. Vigier, Synthesis, structure, and morphology of polymer-silica hybrid nanocomposites based on hydroxyethyl methacrylate Journal of Polymer Science Part B. ,vol. 37, pp. 3172- 3187 ,(1999) , 10.1002/(SICI)1099-0488(19991115)37:22<3172::AID-POLB2>3.0.CO;2-R