Recombination of hydroxyl phases on Ag(110): coexistence of long-range ordered domains of atomic oxygen and hydroxyl

作者: M. Canepa , L. Mattera , E. Narducci

DOI: 10.1016/S0039-6028(96)01093-X

关键词:

摘要: Abstract We report on the thermal evolution of OHAg(110) phase at coverage θ(OH) = 0.66. Combined information, provided by energy helium scattering and angle resolved ultraviolet photoemission spectroscopy, show that recombination OHγ, sub-state, in range 235–255 K produces a new consisting mosaic large ordered oxygen domains OHδ domains. The former present (2 × 1) geometric structure with AgO added rows aligned along 〈001〉 direction while latter (1 2) OHAg chains placed 〈110〉 direction. Further sub-state starting around 260 leading to final O(3 room temperature, proceeds through continuous rearrangement between OH disordered

参考文章(26)
M. Canepa, M. Salvietti, M. Traverso, L. Mattera, Surface reconstruction and thermal desorption: {O}/{Ag(110) } an experimental study Surface Science. pp. 183- 188 ,(1995) , 10.1016/0039-6028(95)00193-X
G. Boato, P. Cantini, Diffraction of Neutral Atoms and Molecules from Crystalline Surfaces Advances in Electronics and Electron Physics Volume 60. ,vol. 60, pp. 95- 160 ,(1983) , 10.1016/S0065-2539(08)60889-6
J.K. Nørskov, Electronic factors in catalysis Progress in Surface Science. ,vol. 38, pp. 103- 144 ,(1991) , 10.1016/0079-6816(91)90007-Q
M Canepa, P Cantini, L Mattera, S Terreni, F Valdenazzi, Electronic States of the Ag(110)-O(n × 1) Phases Studied by Photoemission and Metastable Deexcitation Spectroscopies Physica Scripta. ,vol. 41, pp. 226- 231 ,(1992) , 10.1088/0031-8949/1992/T41/039
Patricia A. Thiel, Theodore E. Madey, The interaction of water with solid surfaces: Fundamental aspects Surface Science Reports. ,vol. 7, pp. 211- 385 ,(1987) , 10.1016/0167-5729(87)90001-X
R. J. MADIX, Molecular Transformations on Single Crystal Metal Surfaces Science. ,vol. 233, pp. 1159- 1166 ,(1986) , 10.1126/SCIENCE.233.4769.1159
M. Canepa, P. Cantini, E. Narducci, M. Salvietti, S. Terreni, L. Mattera, Coexistence of OH phases on Ag(110) Surface Science. ,vol. 343, pp. 176- 184 ,(1995) , 10.1016/0039-6028(95)00819-5
Charles T. Campbell, M.T. Paffett, The adsorption of ethylene oxide on Ag(110) and Pt(111): Relevance to selective olefin oxidation Surface Science. ,vol. 177, pp. 417- 430 ,(1986) , 10.1016/0039-6028(86)90149-4
M.A. Barteau, R.J. Madix, A photoelectron spectroscopic investigation of the interaction between H2O and oxygen on Ag(110) Surface Science Letters. ,vol. 140, pp. A159- 122 ,(1984) , 10.1016/0167-2584(84)90164-6