A trimetallic zinc(II) complex and its catecholase activity
作者： Sunit Kumar Mal , Merry Mitra , Chandra Shekhar Purohit , Rajarshi Ghosh
DOI: 10.1016/J.POLY.2015.08.039
关键词:
摘要: Abstract Synthesis and X-ray crystallographic characterization of a trimetallic zinc(II) complex [Zn3(L)2(fu)2] (1) [H2L = N,N-(salicyaldene)-1,3-diaminopropan-2-ol, fu = 2-furoate] reveal its distorted square pyramid geometry at the two terminal Zn(II) centres octahedral central Zn(II). 1 behaves as an effective catalyst towards oxidation 3,5-di-tert-butylcatechol in 1:1 methanol:dichloromethane mixture to corresponding quinone derivative aerial oxygen. The reaction follows Michaelis–Menten enzymatic kinetics with turnover number (Kcat) 30.40 × 103 h−1.
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