Synthesis, X-ray structure and catecholase activity of an antiferromagnetically coupled trinuclear nickel(II) complex
作者： Abhijit Pal , Sarat Chandra Kumar , Ayon Kanti Ghosh , Chia-Her Lin , Eric Rivière
DOI: 10.1016/J.POLY.2016.03.012
关键词:
摘要: Abstract The synthesis and X-ray crystallographic characterization of one antiferromagnetically coupled trinuclear Ni(II) complex, [Ni3(L)2(OAc)2] (1) [L = N,N-(salicyaldene)-1,3-diaminopropan-2-ol], is reported. It effectively catalyses the oxidation 3,5-ditertiarybutyl catechol to its corresponding quinone in methanol solvent. follows Michaelis–Menten kinetics with a turnover number 3.85 × 103 h−1.
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