Phase transformations in the TiO2-NiO system

作者: V. V. Viktorov , E. A. Belaya , A. S. Serikov

DOI: 10.1134/S0020168512050202

关键词:

摘要: The anatase-rutile phase transition in fine-particle TiO2-NiO oxides has been studied using physicochemical characterization techniques (X-ray diffraction, differential thermal analysis, and mass spectrometry). results demonstrate that NiO additions considerably increase the rate of anataserutile polymorphic transformation. Nickel titanate formation depends on procedures used to prepare both titanium dioxide nickel oxide. In temperature range 700–850°C, anatase rutile prevents formation.

参考文章(5)
D.J. Taylor, P.F. Fleig, R.A. Page, Characterization of nickel titanate synthesized by sol gel processing Thin Solid Films. ,vol. 408, pp. 104- 110 ,(2002) , 10.1016/S0040-6090(02)00143-8
M.S. Sadjadi, K. Zare, S. Khanahmadzadeh, M. Enhessari, Structural characterization of NiTiO3 nanopowders prepared by stearic acid gel method Materials Letters. ,vol. 62, pp. 3679- 3681 ,(2008) , 10.1016/J.MATLET.2008.04.028
Yonghong Ni, Xinghong Wang, Jianming Hong, Nickel titanate microtubes constructed by nearly spherical nanoparticles: Preparation, characterization and properties Materials Research Bulletin. ,vol. 44, pp. 1797- 1801 ,(2009) , 10.1016/J.MATERRESBULL.2009.03.010
Arnulf Muan, Equilibrium Relations in the System NiO-TiO2 in the Temperature Range 1300o to 1750oC Journal of the American Ceramic Society. ,vol. 75, pp. 1357- 1360 ,(1992) , 10.1111/J.1151-2916.1992.TB04194.X