Pyrolysis and catalyzed pyrolysis in the investigation of a neogene shale potential from Valjevo-Mionica Basin, Serbia

作者: Ksenija Stojanović , Aleksandra Šajnović , Tibor J. Sabo , Anatoly Golovko , Branimir Jovančićević

DOI: 10.1021/EF100466F

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摘要: The generative potential of a Neogene shale from Valjevo-Mionica Basin (Serbia) was investigated using conventional pyrolysis and in the presence Pt(IV)- Ru(III)-ions at temperatures 250 400 °C. Total liquid pyrolysate hydrocarbon yields obtained pyrolytic experiments, group composition pyrolysates, distributions saturated biomarkers alkylaromatics pyrolysates showed that is catagenetic stage may be source hydrocarbons. It estimated similar shales found depth 2300−2900 m would become active oil generating rock where minimum temperature necessary for generation between 103 107 used metal ions, demonstrated significant positive effects on total corresponding hydrocarbons, both Comparison results maturity parameters with ratios calculated distribution ...

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