Heavy Petroleum Composition. 4. Asphaltene Compositional Space
作者： Amy M. McKenna , Alan G. Marshall , Ryan P. Rodgers
DOI: 10.1021/EF301747D
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摘要: Asphaltenes and maltenes are defined operationally by solubility (in, e.g., heptane). self-associate in solution form putative nanoaggregates composed of approximately 6–10 asphaltene monomers per subunit. Bulk measurements indicate that asphaltenes more aromatic than contain heteroatoms metals (nitrogen, sulfur, oxygen, nickel, vanadium). Numerous direct imaging, molecular diffusion, mass spectral results agree similar, overlapped carbon number ranges, drastically restricting the acceptable aromaticity “compositional space” for compounds. Thus, when viewed a plot versus given heteroatom class, must occupy different compositional space because they share same range but differ bulk phase behavior. Boduszynski’s work supported overlapping asphaltene/maltene weights, a...
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sci-hub.se 参考文章(88)
Christine A. Hughey, Christopher L. Hendrickson, Ryan P. Rodgers, Alan G. Marshall, Kuangnan Qian, Kendrick mass defect spectrum: a compact visual analysis for ultrahigh-resolution broadband mass spectra. Analytical Chemistry. ,vol. 73, pp. 4676- 4681 ,(2001) , 10.1021/AC010560W
Alan A. Herod, Keith D. Bartle, R. Kandiyoti, Comment on a Paper by Mullins, Martinez-Haya, and Marshall “Contrasting Perspective on Asphaltene Molecular Weight. This Comment vs the Overview of A. A. Herod, K. D. Bartle, and R. Kandiyoti” Energy & Fuels. ,vol. 22, pp. 4312- 4317 ,(2008) , 10.1021/EF8006036
Eric Y. Sheu, Petroleum AsphalteneProperties, Characterization, and Issues Energy & Fuels. ,vol. 16, pp. 74- 82 ,(2002) , 10.1021/EF010160B
Thomas F. Headen, Edo S. Boek, Jörg Stellbrink, Ulrich M. Scheven, Small Angle Neutron Scattering (SANS and V-SANS) Study of Asphaltene Aggregates in Crude Oil Langmuir. ,vol. 25, pp. 422- 428 ,(2009) , 10.1021/LA802118M
Clifford C. Walters, Kuangnan Qian, Chunping Wu, Anthony S. Mennito, Zhibin Wei, Proto-solid bitumen in petroleum altered by thermochemical sulfate reduction Organic Geochemistry. ,vol. 42, pp. 999- 1006 ,(2011) , 10.1016/J.ORGGEOCHEM.2011.08.001
Klaus H. Altgelt, Mieczyslaw M. Boduszynski, Composition of heavy petroleums. 3. An improved boiling point-molecular weight relation Energy & Fuels. ,vol. 6, pp. 68- 72 ,(1992) , 10.1021/EF00031A010
Otto P. Strausz, Ping'an Peng, Juan Murgich, About the Colloidal Nature of Asphaltenes and the MW of Covalent Monomeric Units Energy & Fuels. ,vol. 16, pp. 809- 822 ,(2002) , 10.1021/EF0002795
Alan G. Marshall, Christopher L. Hendrickson, George S. Jackson, Fourier transform ion cyclotron resonance mass spectrometry: A primer Mass Spectrometry Reviews. ,vol. 17, pp. 1- 35 ,(1998) , 10.1002/(SICI)1098-2787(1998)17:1<1::AID-MAS1>3.0.CO;2-K
Stone D.-H. Shi, Jared J. Drader, Michael A. Freitas, Christopher L. Hendrickson, Alan G. Marshall, Comparison and interconversion of the two most common frequency-to-mass calibration functions for Fourier transform ion cyclotron resonance mass spectrometry International Journal of Mass Spectrometry. ,vol. 195, pp. 591- 598 ,(2000) , 10.1016/S1387-3806(99)00226-2
Ksenija Stojanović, Aleksandra Šajnović, Tibor J. Sabo, Anatoly Golovko, Branimir Jovančićević, Pyrolysis and catalyzed pyrolysis in the investigation of a neogene shale potential from Valjevo-Mionica Basin, Serbia Energy & Fuels. ,vol. 24, pp. 4357- 4368 ,(2010) , 10.1021/EF100466F