Thermodynamic admissibility of the reptation model

作者: Scott T. Milner

DOI: 10.1122/1.1631424

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摘要: In a recent paper, Ottinger and Beris assert that the celebrated Doi–Edwards (DE) model for entangled polymer dynamics is incompatible with so-called “GENERIC” form of nonequilibrium thermodynamics. Simply put, they claim DE tube inconsistent principle virtual work. I show correct choice effective Hamiltonian, namely full configurational entropy, stress tensor does in fact result from work argument.

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