Solvothermal synthesis of CZTS nanoparticles in ethanol: Preparation and characterization

作者: Xinlong Yan , Xiaoyan Hu , Sridhar Komarneni

DOI: 10.3938/JKPS.66.1511

关键词:

摘要: In this work, a low-cost, non-toxic and convenient one-pot solvothermal route to synthesize Cu2ZnSnS4 (CZTS) nanoparticles is reported. The effects of temperature reaction time on the structure, morphology optical properties as-synthesized product were investigated by using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission (TEM), energy dispersive analysis (EDX) measurements photoelectron spectroscopy (XPS). results showed that crystallinity CZTS powders was influenced time. band gap selected samples near optimum value for photovoltaic solar conversion in single-band-gap device.

参考文章(38)
Alex Redinger, Susanne Siebentritt, Coevaporation of Cu2ZnSnSe4 thin films Applied Physics Letters. ,vol. 97, pp. 092111- ,(2010) , 10.1063/1.3483760
Mahesh Suryawanshi, Seung Wook Shin, Woo RI Bae, Kishor Gurav, Myun Gil Kang, Ganesh Agawane, Pramod Patil, Jae Ho Yun, Jeong Yong Lee, Annasaheb Moholkar, Jin Hyeok Kim, None, Kesterite CZTS nanocrystals: pH‐dependent synthesis Physica Status Solidi (a). ,vol. 211, pp. 1531- 1534 ,(2014) , 10.1002/PSSA.201330384
M. Cao, Y. Shen, A mild solvothermal route to kesterite quaternary Cu2ZnSnS4 nanoparticles Journal of Crystal Growth. ,vol. 318, pp. 1117- 1120 ,(2011) , 10.1016/J.JCRYSGRO.2010.10.071
N.M. Shinde, P.R. Deshmukh, S.V. Patil, C.D. Lokhande, Aqueous chemical growth of Cu2ZnSnS4 (CZTS) thin films: Air annealing and photoelectrochemical properties Materials Research Bulletin. ,vol. 48, pp. 1760- 1766 ,(2013) , 10.1016/J.MATERRESBULL.2012.12.053
Xin Zhang, Xuezhao Shi, Weichun Ye, Chuanli Ma, Chunming Wang, Electrochemical deposition of quaternary Cu(2)ZnSnS(4) thin films as potential solar cell material Applied Physics A. ,vol. 94, pp. 381- 386 ,(2009) , 10.1007/S00339-008-4815-5
Xinlong Yan, Elizabeth Michael, Sridhar Komarneni, Jeffrey R. Brownson, Zi-Feng Yan, Microwave-hydrothermal/solvothermal synthesis of kesterite, an emerging photovoltaic material Ceramics International. ,vol. 40, pp. 1985- 1992 ,(2014) , 10.1016/J.CERAMINT.2013.07.108
Mei Li, Wen-Hui Zhou, Jie Guo, Yan-Li Zhou, Ze-Liang Hou, Jie Jiao, Zheng-Ji Zhou, Zu-Liang Du, Si-Xin Wu, Synthesis of Pure Metastable Wurtzite CZTS Nanocrystals by Facile One-Pot Method Journal of Physical Chemistry C. ,vol. 116, pp. 26507- 26516 ,(2012) , 10.1021/JP307346K
Pengcheng Dai, Guan Zhang, Yuncheng Chen, Hechun Jiang, Zhenyu Feng, Zhaojun Lin, Jinhua Zhan, Porous copper zinc tin sulfide thin film as photocathode for double junction photoelectrochemical solar cells Chemical Communications. ,vol. 48, pp. 3006- 3008 ,(2012) , 10.1039/C2CC17652A
W. C. Liu, B. L. Guo, X. S. Wu, F. M. Zhang, C. L. Mak, K. H. Wong, Facile hydrothermal synthesis of hydrotropic Cu2ZnSnS4 nanocrystal quantum dots: band-gap engineering and phonon confinement effect Journal of Materials Chemistry. ,vol. 1, pp. 3182- 3186 ,(2013) , 10.1039/C3TA00357D
Samrat Sarkar, Kaustav Bhattacharjee, G. C. Das, K. K. Chattopadhyay, Self-sacrificial template directed hydrothermal route to kesterite-Cu2ZnSnS4 microspheres and study of their photo response properties CrystEngComm. ,vol. 16, pp. 2634- 2644 ,(2014) , 10.1039/C3CE42229A