Aldol Type Condensations of β-Keto Ester Dianions

作者: Stuart Nicholas Huckin , Larry Weiler

DOI: 10.1139/V74-311

关键词:

摘要: The dianion of methyl acetoacetate reacts with ketones and aldehydes to yield δ -hydroxy-β-keto esters. These hydroxy esters can be dehydrated the corresponding γ,δ-unsaturated-β-keto which are useful in annelation reactions form cyclic β-keto does not appear undergo conjugate addition simple α,β-unsaturated ketones, instead only carbonyl occurs.

参考文章(2)
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Edwin M. Kaiser, Lithium annual survey covering the year 1974 Journal of Organometallic Chemistry. ,vol. 98, pp. 1- 115 ,(1975) , 10.1016/S0022-328X(00)89854-X