Micellization of Pentanediyl-1,5-bis(hydroxyethylmethyl hexadecylammonium Bromide) as a Cationic Gemini Surfactant in Aqueous Solutions: Investigation Using Conductometry and Fluorescence Techniques
作者： R. Zarganian , A. K. Bordbar , R. Amiri , M. Tamannaei , A. R. Khosropour
DOI: 10.1007/S10953-011-9694-2
关键词:
摘要: Pentanediyl-1,5-bis (hydroxyethylmethylhexadecylammonium bromide) was synthesized and characterized as a type of novel gemini cationic surfactant. Its solution properties were determined at various temperatures by conductivity measurements the fluorescence quenching technique. The CMC increased in range 1.85 to 2.77 μmol⋅L−1 temperature increased. aggregation number concentrations NaBr solutions pyrene. thermodynamic parameters micellization using mass law equation values ΔG °, ΔH °and ΔS ° for process.
springer.com
sci-hub.se 参考文章(26)
B. S. Sekhon, Gemini (dimeric) surfactants Resonance. ,vol. 9, pp. 42- 49 ,(2004) , 10.1007/BF02834987
S. K. Hait, S. P. Moulik, Gemini surfactants: A distinct class of self-assembling molecules Current Science. ,vol. 82, pp. 1101- 1111 ,(2002)
Krister Holmberg, Novel surfactants : preparation, applications, and biodegradability Marcel Dekker. ,(1998)
Pasupati Mukerjee, John R. Cardinal, Benzene derivatives and naphthalene solubilized in micelles. Polarity of microenvironments, location and distribution in micelles, and correlation with surface activity in hydrocarbon-water systems The Journal of Physical Chemistry. ,vol. 82, pp. 1620- 1627 ,(1978) , 10.1021/J100503A010
J. J. Galán, A. González-Pérez, J. R. Rodríguez, Micellization of dodecyldimethylethyl- ammonium bromide in aqueous solution Journal of Thermal Analysis and Calorimetry. ,vol. 72, pp. 465- 470 ,(2003) , 10.1023/A:1024552911066
Tohru Inoue, Hayato Ebina, Bin Dong, Liqiang Zheng, Electrical conductivity study on micelle formation of long-chain imidazolium ionic liquids in aqueous solution. Journal of Colloid and Interface Science. ,vol. 314, pp. 236- 241 ,(2007) , 10.1016/J.JCIS.2007.05.052
S. Manne, T. E. Schäffer, Q. Huo, P. K. Hansma, D. E. Morse, G. D. Stucky, I. A. Aksay, Gemini Surfactants at Solid−Liquid Interfaces: Control of Interfacial Aggregate Geometry Langmuir. ,vol. 13, pp. 6382- 6387 ,(1997) , 10.1021/LA970070S
S. Warwel, F. Brüse, H. Schier, Glucamine-based gemini surfactants I: Gemini surfactants from long-chain N-alkyl glucamines and α,ω-diepoxides Journal of Surfactants and Detergents. ,vol. 7, pp. 181- 186 ,(2004) , 10.1007/S11743-004-0302-1
B.A. Bidlingmeyer, S.N. Deming, W.P. Price, B. Sachok, M. Petrusek, Retention mechamism for reversed-phase ion-pair liquid chromatography Journal of Chromatography A. ,vol. 186, pp. 419- 434 ,(1979) , 10.1016/S0021-9673(00)95264-6
González-Pérez A., J. Del Castillo, Czapkiewicz J., Rodríguez J., Micellization of decyl- and dodecyldimethylbenzylammonium bromides at various temperatures in aqueous solutions Colloid and Polymer Science. ,vol. 280, pp. 503- 508 ,(2002) , 10.1007/S00396-001-0635-2