Liquid solubilization dynamicsII. Flux enhancement by interface gel formation
作者： Kevin T Raterman , Joseph A Shaeiwitz
DOI: 10.1016/0021-9797(84)90163-2
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摘要: Abstract Dynamic solubilization studies were conducted to determine the mechanism of incorporation oleic acid into aqueous sodium taurodeoxycholate solutions at 37°C in which apparent diffusion limit mixed micelles was exceeded. The effects pH, added NaCl, and surfactant type on flux determined by means a membrane-modified liquid/liquid stirred cell for this model fatty digestion system. enhanced mass transfer sufficiently high pH concentration can be satisfactorily explained formation an oil/aqueous liquid crystalline phase interface. Under flow conditions may sheared from interface subsequently solubilized bulk as micelle or microemulsion. Experiments under non-flow support proposed mechanism.
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sci-hub.se 参考文章(23)
Philip Alan Winsor, Solvent properties of amphiphilic compounds Butterworth's Scientific Publications. ,(1954)
J.B. Lewis, The mechanism of mass transfer of solutes across liquid-liquid interfaces Chemical Engineering Science. ,vol. 3, pp. 260- 278 ,(1954) , 10.1016/0009-2509(54)80008-X
G.B Thurston, J.L Salager, R.S Schechter, Effects of salinity on the viscosity and birefringence of a microemulsion system Journal of Colloid and Interface Science. ,vol. 70, pp. 517- 523 ,(1979) , 10.1016/0021-9797(79)90059-6
George D. J. Phillies, Reactive contribution to the apparent translational diffusion coefficient of a micelle The Journal of Physical Chemistry. ,vol. 85, pp. 3540- 3541 ,(1981) , 10.1021/J150623A034
Joseph A. Shaeiwitz, Kevin T. Raterman, Modeling and calculation of interfacial resistances with energy profiles Industrial & Engineering Chemistry Fundamentals. ,vol. 21, pp. 154- 161 ,(1982) , 10.1021/I100006A009
Chente Huang, D. Fennell Evans, E.L. Cussler, Linoleic acid solubilization with a spinning liquid disc joint international conference on information sciences. ,vol. 82, pp. 499- 506 ,(1981) , 10.1016/0021-9797(81)90391-X
W Shankland, The ionic behavior of fatty acids solubilized by bile salts. Journal of Colloid and Interface Science. ,vol. 34, pp. 9- 25 ,(1970) , 10.1016/0021-9797(70)90253-5
Robert N. Healy, Ronald L. Reed, Physicochemical Aspects of Microemulsion Flooding Society of Petroleum Engineers Journal. ,vol. 14, pp. 491- 501 ,(1974) , 10.2118/4583-PA
A. K. M. Shamsul Huq, S. A. K. Lodhi, Distribution of Benzoic Acid between Benzene and Water and Dimerization of Benzoic Acid in Benzene1a The Journal of Physical Chemistry. ,vol. 70, pp. 1354- 1358 ,(1966) , 10.1021/J100877A003
LAWRENCE R. STOWE, JOSEPH A. SHAEIWITZ, HYDRODYNAMICS AND MASS TRANSFER CHARACTERISTICS OF A LIQUID/LIQUID STIRRED CELL Chemical Engineering Communications. ,vol. 11, pp. 17- 26 ,(1981) , 10.1080/00986448108910985