Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes.
作者： Chenxi Ma , Anthony F. Hill
DOI: 10.1039/C8DT04813D
关键词:
摘要: The reactions of [RuCl(R)(CO)(PPh3)2] (R = CHCHPh, Ph) with Na[H2B(mt)2] (mt N-methyl-2-mercaptoimidazolyl) transiently provide [Ru(R)(CO)(PPh3){κ3-H,S,S′-H2B(mt)2}] which each evolve to the ruthenaboratrane [Ru(CO)(PPh3)2{κ3-B,S,S′-BH(mt)2}](Ru→B)8. phosphine ligands may be selectively replaced complexes [Ru(CO)(L)(PPh3){κ3-B,S,S′-BH(mt)2}] (L CO, PMe2Ph) and [Ru(CO)L2{κ3-B,S,S′-BH(mt)2}] PMe2Ph, P(OMe)3, L2 Z-Ph2PCHCHPPh2) with, in case, retention ruthenium–boron dative bond.
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sci-hub.se 参考文章(115)
Sébastien Bontemps, Heinz Gornitzka, Ghenwa Bouhadir, Karinne Miqueu, Didier Bourissou, Rhodium(I) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal→Borane Interaction Angewandte Chemie. ,vol. 45, pp. 1611- 1614 ,(2006) , 10.1002/ANIE.200503649
Dipak Kumar Roy, Anangsha De, Subhankar Panda, Babu Varghese, Sundargopal Ghosh, Chemistry of N,S‐Heterocyclic Carbene and Metallaboratrane Complexes: A New η3‐BCC‐Borataallyl Complex Chemistry: A European Journal. ,vol. 21, pp. 13732- 13738 ,(2015) , 10.1002/CHEM.201501014
R. S. Anju, Dipak Kumar Roy, Bijan Mondal, K. Yuvaraj, C. Arivazhagan, Koushik Saha, Babu Varghese, Sundargopal Ghosh, Reactivity of diruthenium and dirhodium analogues of pentaborane(9): agostic versus boratrane complexes. Angewandte Chemie. ,vol. 53, pp. 2873- 2877 ,(2014) , 10.1002/ANIE.201310416
Georg C. Rudolf, Alex Hamilton, A. Guy Orpen, Gareth R. Owen, A 'sting' on Grubbs' catalyst: an insight into hydride migration between boron and a transition metal. Chemical Communications. pp. 553- 555 ,(2009) , 10.1039/B816036H
Nikolaos Tsoureas, Yu-Ying Kuo, Mairi F. Haddow, Gareth R. Owen, Double addition of H2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres Chemical Communications. ,vol. 47, pp. 484- 486 ,(2011) , 10.1039/C0CC02245D
Marie Sircoglou, Sébastien Bontemps, Maxime Mercy, Nathalie Saffon, Masashi Takahashi, Ghenwa Bouhadir, Laurent Maron, Didier Bourissou, Transition‐Metal Complexes Featuring Z‐Type Ligands: Agreement or Discrepancy between Geometry and dn Configuration? Angewandte Chemie. ,vol. 46, pp. 8583- 8586 ,(2007) , 10.1002/ANIE.200703518
Keliang Pang, Stephanie M. Quan, Gerard Parkin, Palladium complexes with Pd→B dative bonds: Analysis of the bonding in the palladaboratrane compound [κ4-B(mimBut)3]Pd(PMe3) Chemical Communications. pp. 5015- 5017 ,(2006) , 10.1039/B611654J
Gareth R. Owen, P. Hugh Gould, Jonathan P. H. Charmant, Alex Hamilton, Saowanit Saithong, A new hybrid scorpionate ligand: a study of the metal-boron bond within metallaboratrane complexes. Dalton Transactions. ,vol. 39, pp. 392- 400 ,(2010) , 10.1039/B911651F
Sébastien Bontemps, Marie Sircoglou, Ghenwa Bouhadir, Horst Puschmann, Judith AK Howard, Philip W Dyer, Karinne Miqueu, Didier Bourissou, None, Ambiphilic diphosphine-borane ligands: metal-->borane interactions within isoelectronic complexes of rhodium, platinum and palladium. Chemistry: A European Journal. ,vol. 14, pp. 731- 740 ,(2008) , 10.1002/CHEM.200701027
James D. E. T. Wilton-Ely, Sanaz J. Honarkhah, Ming Wang, Derek A. Tocher, Alexandra M. Z. Slawin, σ-Organyl complexes of ruthenium and osmium supported by a mixed-donor ligand Dalton Transactions. pp. 1930- 1939 ,(2005) , 10.1039/B501906K