New Acyclic Chalcogen Bearing Ligands and their Complexation Reactions

作者: Jai Deo Singh , Marilyn Daisy Milton , Bishan L. Khandelwal , S. Karthikeyan , T.P. Singh

DOI: 10.1080/10426509808545955

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摘要: Two (N 3 Se 2) type acyclic Schiff-bases, [{PhSe(CH2)n N=C(CH3)}2C5H3N] (n = 2,3), and their complexes with Cd(II) have been synthesized characterized. The geometry around central cadmium has assigned on the basis of physicochemical spectral studies.Structure complex [PhSe(CH2)3NC(CH3)C5H5N.C(CH3)NH] .CdCl2 confirmed by single crystal X-ray diffraction method.

参考文章(11)
Yoshiaki Nishibayashi, Jai Deo Singh, Yasuyoshi Arikawa, Sakae Uemura, Masanobu Hidai, Rhodium(I)-, iridium(I)-, and ruthenium(II)-catalyzed asymmetric transfer hydrogenation of ketones using diferrocenyl dichalcogenides as chiral ligands Journal of Organometallic Chemistry. ,vol. 531, pp. 13- 18 ,(1997) , 10.1016/S0022-328X(96)06681-8
Wakgari Hirpo, Sandeep Dhingra, Anthony C. Sutorik, Mercouri G. Kanatzidis, Synthesis of mixed copper-indium chalcogenolates. Single-source precursors for the photovoltaic materials CuInQ2 (Q = S, Se) Journal of the American Chemical Society. ,vol. 115, pp. 1597- 1599 ,(1993) , 10.1021/JA00057A067
Yoshiaki Nishibayashi, Kyohei Segawa, Jai Deo Singh, Shin-ichi Fukuzawa, Kouichi Ohe, Sakae Uemura, Novel Chiral Ligands, Diferrocenyl Dichalcogenides and Their Derivatives, for Rhodium- and Iridium-Catalyzed Asymmetric Hydrosilylation Organometallics. ,vol. 15, pp. 370- 379 ,(1996) , 10.1021/OM950533U
M. L. Steigerwald, C. R. Sprinkle, Organometallic synthesis of II-VI semiconductors. 1. Formation and decomposition of bis(organotelluro)mercury and bis(organotelluro)cadmium compounds Journal of the American Chemical Society. ,vol. 109, pp. 7200- 7201 ,(1987) , 10.1021/JA00257A055
Y. Cheng, T. J. Emge, J. G. Brennan, PYRIDINESELENOLATE COMPLEXES OF COPPER AND INDIUM : PRECURSORS TO CUSEX AND IN2SE3 Inorganic Chemistry. ,vol. 35, pp. 7339- 7344 ,(1996) , 10.1021/IC9603969